Abstract
A kinetic model of benzene hydrogenation on a sulfide hydropurification catalyst (Ni,Mo)/Al2O3 has been developed. The model describes well the experimental data obtained under unsteady-state conditions and relies on the assumption that the catalyst surface contains only one type of active sites, i.e., Ni atoms in the sulfide bimetallic complex, and makes allowance for the transition of active sites into inactive sites.
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Ivanov, E., Reshetnikov, S., Sidyakin, M. et al. Benzene hydrogenation on sulfide catalyst under unsteady-state conditions. Reaction Kinetics and Catalysis Letters 78, 389–395 (2003). https://doi.org/10.1023/A:1022606532254
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DOI: https://doi.org/10.1023/A:1022606532254