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Generalized criterion of solvent polarity as a tool for control of chromatographic process

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Abstract

The generalized (reductive) criterion of solvent polarity was obtained by the method of multiparametric optimization of the Snyder index P", Hildebrand parameter δ T , permittivity ε r , and solvatochromism parameter E T (30). Possibilities of employing this criterion for estimation of the elution power of normal and reversed mobile phases used in high-performance liquid chromatography were considered.

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Authors and Affiliations

  1. Voronezh State Technological Academy, 19 prosp. Revolyutsii, 394017, Voronezh, Russian Federation

    O. B. Rudakova

  2. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    I. P. Sedishev

Authors
  1. O. B. Rudakova
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  2. I. P. Sedishev
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Rudakova, O.B., Sedishev, I.P. Generalized criterion of solvent polarity as a tool for control of chromatographic process. Russian Chemical Bulletin 52, 55–62 (2003). https://doi.org/10.1023/A:1022475710649

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