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Preparation of Linear π-Conjugated Coordination Polymers Having Ruthenium(II) Complex in the Main Chain

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Abstract

Soluble π-conjugated coordination polymers having a ruthenium(II) complex in the main chain were prepared from a “soluble metal complex monomer” and a “bridging ligand” via coordination. Refluxing of an ethanol-water suspension containing (4,4′-dinonyl-2,2′-bipyridyl)Ru(III) with 2,3-bis(2′-pyridyl)pyrazine gave the coordination polymer. The resulting polymer was soluble in common organic solvents. The structure was confirmed by uv/vis spectra and gpc analysis.

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Authors and Affiliations

  1. Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606-8501, Japan

    Gen-ichi Konishi, Kensuke Naka & Yoshiki Chujo

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  1. Gen-ichi Konishi
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  2. Kensuke Naka
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  3. Yoshiki Chujo
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Correspondence to Yoshiki Chujo.

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Konishi, Gi., Naka, K. & Chujo, Y. Preparation of Linear π-Conjugated Coordination Polymers Having Ruthenium(II) Complex in the Main Chain. Journal of Inorganic and Organometallic Polymers 9, 179–188 (1999). https://doi.org/10.1023/A:1021611128087

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  • DOI: https://doi.org/10.1023/A:1021611128087

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