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Binuclear and mononuclear cobalt(II), nickel(II) and copper(II) complexes of 4,4′-bis(alkylaminoisonitrosoacetyl)diphenyl-methane derivatives

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Abstract

4,4′-Bis(chloroacetyl)diphenylmethane has been prepared from ClCH2COCl and Ph2CH2. 4,4′-Methylenebis(phenylglyoxylohydroximoyl chloride has also been obtained. Four new substituted 4,4′-bis(alkylaminoisonitrosoacetyl)diphenylmethanes (ligands) have been prepared from 4,4′-methylenebis(phenylglyoxylohydroximoyl chloride) and the corresponding amines. The NiII, CuII and CoII complexes of these ligands were prepared and their structures were identified using AAS, i.r., 1H-n.m.r. spectral data, elemental analyses and magnetic susceptibility measurements.

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Karipcin, F., Uçan, H.İ. & Karataş, İ. Binuclear and mononuclear cobalt(II), nickel(II) and copper(II) complexes of 4,4′-bis(alkylaminoisonitrosoacetyl)diphenyl-methane derivatives. Transition Metal Chemistry 27, 813–817 (2002). https://doi.org/10.1023/A:1021315931250

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