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Substituted Butanolides and Butenolides: XVI. Oxidative and Hydrolytic Transformations of Butanolide Fused to Dihydropyrazole Ring

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Abstract

Reactions of 3a,4,6,6a-tetrahydro-3H-furo[3,4-c]pyrazol-6-one with chlorine and bromine give the corresponding 2,6-dihydro-4H-furo[3,4-c]pyrazol-6-one hydrohalides. Hydrolysis of 3a,4,6,6a-tetrahydro-3H-furo[3,4-c]pyrazol-6-one is accompanied by oxidation of the dihydropyrazole ring to pyrazole and opening of the lactone ring.

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Tyukhteneva, Z.I., Badovskaya, L.A. Substituted Butanolides and Butenolides: XVI. Oxidative and Hydrolytic Transformations of Butanolide Fused to Dihydropyrazole Ring. Russian Journal of Organic Chemistry 38, 1042–1045 (2002). https://doi.org/10.1023/A:1020818116077

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  • DOI: https://doi.org/10.1023/A:1020818116077

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