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Highly Dispersed and Stable Supported Metal Catalysts Prepared by Solid Phase Crystallization Method

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Abstract

Starting from the precursors containing active metal species in the crystal structure, highly dispersed supported metal catalysts have been prepared by the calcination-reduction treatment. This method is named as “solid phase crystallization (spc)” method and was compared with the conventional impregnation (imp) method. As the precursors, both perovskite-type and hydrotalcite-type oxides have been utilized for preparing various supported metal catalysts, which were successfully applied for the reforming of CH4 and the decomposition of methanol. Especially spc-Ni/Mg–Al catalyst prepared from the hydrotalcite-type precursors showed high activity as well as high sustainability for the hydrogen production from methane.

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REFERENCES

  1. R.G. Mandelik, D.S. Newsome, and P. Kellogg, in: Encyclopedia of Chemical Technology, Vol. 12, eds. R.E. Kirk and D.F. Othmer, 3rd edn. p. 938. (Wiley-Interscience, New York, 1980).

    Google Scholar 

  2. M.A. Pena, J.P. Gomez and J.L.G. Fierro, Appl. Catal. A 144 (1996) 7.

    Google Scholar 

  3. J.N. Armor, Appl. Catal. A 176 (1999) 159.

    Google Scholar 

  4. K. Nomura, T. Goda, Y. Ujihira, T. Hayakawa and K. Takehira, Hyperfine Int. 69 (1991) 835.

    Google Scholar 

  5. K. Nomura, T. Hayakawa, K. Takehira and Y. Ujihira, Appl. Catal. A 101 (1993) 63.

    Google Scholar 

  6. T. Hayakawa, H. Orita, M. Shimizu, K. Takehira, A.G. Andersen, K. Nomura and Y. Ujihira, Catal. Lett. 16 (1992) 359.

    Google Scholar 

  7. G. Yi, T. Hayakawa, A.G. Andersen, K. Suzuki, S. Hamakawa, A.P.E. York, M. Shimizu and K. Takehira, Catal. Lett. 38 (1996) 189.

    Google Scholar 

  8. T. Hayakawa, A.G. Andersen, H. Orita, M. Shimizu and K. Takehira, Catal. Lett. 16 (1992) 373.

    Google Scholar 

  9. K. Nomura, Y. Ujihira, T. Hayakawa and K. Takehira, Appl. Catal. A 137 (1996) 25.

    Google Scholar 

  10. K. Nomura, Z. Homonnay, A. Vertes, V. Chechersky, A. Nath, Y. Ujihira, T. Hayakawa and K. Takehira, Czechoslovak J. Phys. 47 (1997) 517.

    Google Scholar 

  11. T. Hayakawa, H. Harihara, A.G. Andersen, K. Suzuki, H. Yasuda, M. Shimizu and K. Takehira, Sekiyu Gakkaishi 39 (1996) 314.

    Google Scholar 

  12. T. Hayakawa, M. Shimizu, K. Suzuki and K. Takehira, Catal. Lett. 23 (1993) 59.

    Google Scholar 

  13. A.G. Andersen, T. Hayakawa, T. Tsunoda, H. Orita, M. Shimizu and K. Takehira, Catal. Lett. 18 (1993) 37.

    Google Scholar 

  14. T. Hayakawa, A.G. Andersen, M. Shimizu, K. Suzuki and K. Takehira, Catal. Lett. 22 (1993) 307.

    Google Scholar 

  15. K. Takehira, T. Hayakawa, H. Harihara, A.G. Andersen, K. Suzuki and M. Shimizu, Catal. Today 24 (1995) 237.

    Google Scholar 

  16. T. Hayakawa, H. Harihara, A.G. Andersen, A.P.E. York, K. Suzuki, H. Yasuda and K. Takehira, Angew. Chem., Int. Ed. Engl. 35 (1996) 192.

    Google Scholar 

  17. T. Hayakawa, H. Harihara, A.G. Andersen, K. Suzuki, H. Yasuda, T. Tsunoda, S. Hamakawa, A.P.E. York, Y.S. Yoon, M. Shimizu and K. Takehira, Appl. Catal. A 149 (1997) 391.

    Google Scholar 

  18. R. Shiozaki, A.G. Andersen, T. Hayakawa, S. Hamakawa, K. Suzuki, M. Shimizu and K. Takehira, Stud. Surf. Sci. Catal. 110 (1997) 701.

    Google Scholar 

  19. R. Shiozaki, A.G. Andersen, T. Hayakawa, S. Hamakawa, K. Suzuki, M. Shimizu and K. Takehira, J. Chem. Soc., Faraday Trans. 93 (1997) 3235.

    Google Scholar 

  20. K. Takehira, T. Shishido and M. Kondo, Shokubai 42 (2000) 354.

    Google Scholar 

  21. K. Takehira, T. Shishido and M. Kondo, J. Catal. 207 (2002) 307.

    Google Scholar 

  22. H. Shimada, M. Imamura, N. Matsubayashi, T. Sato, T. Hayakawa, K. Takehira, S. Kure, A. Kinoshita and A. Nishijima, J. Phys IV France 7 (1997) C2-919.

    Google Scholar 

  23. J. Jia, P. Wang, K. Ito, H. Morioka, Y. Wang, T. Shishido and K. Takehira, Catal. Lett. 76 (2001) 183.

    Google Scholar 

  24. A.G. Andersen, T. Hayakawa, K. Suzuki, M. Shimizu and K. Takehira, Catal. Lett. 27 (1994) 221.

    Google Scholar 

  25. S. Hamakawa, R. Shiozaki, T. Hayakawa, K. Suzuki, K. Murata, K. Takehira, M. Koizumi, J. Nakamura and T. Uchijima, J. Electrochem. Soc. 147 (2000) 839.

    Google Scholar 

  26. S. Hamakawa, T. Hayakawa, K. Suzuki, K. Murata, K. Takehira, S. Yoshino, J. Nakamura and T. Uchijima, Solid State Ionics 136-137 (2000) 761.

    Google Scholar 

  27. T. Shishido, M. Sukenobu, H. Morioka, M. Kondo, Y. Wang, K. Takaki and K. Takehira, Appl. Catal. A 223 (2002) 35.

    Google Scholar 

  28. H. Morioka, Y. Shimidzu, M. Sukenobu, K. Ito, E. Tanabe, T. Shishido and K. Takehira, Appl. Catal. A, 215 (2001) 11.

    Google Scholar 

  29. S. Suzuki, Hayakawa, S. Hamakawa, K. Suzuki, T. Shishido and K. Takehira, Stud. Surf. Sci. Catal. 119 (1998) 783.

    Google Scholar 

  30. T. Hayakawa, S. Suzuki, S. Hamakawa, K. Suzuki, T. Shishido and K. Takehira, Appl. Catal. A, 183 (1999) 273.

    Google Scholar 

  31. K. Takehira, T. Shishido, M. Kondo, R. Furukawa, E. Tanabe, K. Ito, S. Hamakawa and T. Hayakawa, Stud. Surf. Sci. Catal. 130 (2000) 3525.

    Google Scholar 

  32. T. Shishido, M. Sukenobu, H. Morioka, R. Furukawa, H. Shirahase and K. Takehira, Catal. Lett. 73 (2001) 21.

    Google Scholar 

  33. A.I. Tsyganok, K. Suzuki, S. Hamakawa, K. Takehira and T. Hayakawa, Chem. Lett. (2001) 24.

  34. A.I. Tsyganok, K. Suzuki, S. Hamakawa, K. Takehira and T. Hayakawa, Catal. Lett. 77 (2001) 75.

    Google Scholar 

  35. T. Shishido, W. Peng, T. Kosaka and K. Takehira, Sholubai 44, (2002) 131.

    Google Scholar 

  36. H. Morioka, Y. Yamamoto, K. Ito, E. Tanabe, T. Shishido and K. Takehira, Shokubai 43 (2001) 90.

    Google Scholar 

  37. R. Shiozaki, T. Hayakawa, T. Ishii, M. Kumagai, S. Hamakawa, K. Suzuki, T. Ito, T. Shishido and K. Takehira, Catal. Lett. 58 (1999) 131.

    Google Scholar 

  38. T. Shishido, H. Sameshima, T. Hayakawa, S. Hamakawa, E. Tanabe, K. Ito and K. Takehira, Stud. Surf. Sci. Catal. 130 (2000) 2117.

    Google Scholar 

  39. T. Shishido, H. Sameshima and K. Takehira, Topics in Catalysis in press.

  40. A.T. Ashcroft, A.K. Cheetham, J.S. Foord, M.L.H. Green, C.P. Grey, A.J. Murrell and P.D.F. Vernon, Nature 344 (1990) 319.

    Google Scholar 

  41. P. D. F. Vernon, M.L.H. Green, A. K. Cheetham and A. T. Ashcroft, Catal. Lett. 6 (1990) 181.

    Google Scholar 

  42. R. H. Jones, A. T. Ashcroft, D. Waller, A. K. Cheetham and J. M. Thomas, Catal. Lett. 8 (1991) 169.

    Google Scholar 

  43. J. B. Claridge, M.L.H. Green, S. C. Tsang, A.P.E. York, A. T. Ashcroft and P. D. Battle, Catal. Lett. 22 (1993) 299.

    Google Scholar 

  44. D. A. Hickman and L. D. Schmidt, Science 259 (1993) 343.

    Google Scholar 

  45. V. R. Choudhary, A. M. Rajput and B. Prabhakar, J. Catal. 139 (1993) 326.

    Google Scholar 

  46. D. Dissnayake, M. P. Rosynek, K.C.C. Kharas and J. H. Lunsford, J. Catal. 132 (1991) 117.

    Google Scholar 

  47. D. Dissanayake, M. P. Rosynek and J. H. Lunsford, J. Phys. Chem. 97 (1993) 3644.

    Google Scholar 

  48. J. Nakamura, K. Kubushiro and T. Uchijima, Stud. Surf. Sci. Catal. 77 (1993) 373.

    Google Scholar 

  49. K. Nakagawa, N. Ikenaga, Y. Teng, T. Kobayashi and T. Suzuki, J. Catal. 186 (1999) 405.

    Google Scholar 

  50. L. Basini, A. Guarinoni and A. Aragno, J. Catal. 190 (2000) 284.

    Google Scholar 

  51. F. Basile, L. Basini, M. D'Amore, G. Fornasari, A. Guarinoni, D. Matteuzzi, G. Del Pierro, F. Trifiro and A. Vaccari, J. Catal. 173 (1998) 247.

    Google Scholar 

  52. M. Audier, A. Oberlin, M. Oberlin, M. Coulon and L. Bonnetain, Carbon 19 (1981) 217.

    Google Scholar 

  53. C. H. Bartholomew, Catal. Rev.-Sci. Eng. 24 (1982) 67.

    Google Scholar 

  54. O. Yamazaki, T. Nozaki, K. Omata and K. Fujimoto, Chem. Lett. (1992) 1953.

  55. L. Simon, F. Garin and G. Maire, Appl. Catal. B. 11 (1997) 167.

    Google Scholar 

  56. L. G. Tejuca and J.L.G. Fierro (eds.), Properties and Applications of Perovskite-Type Oxides, (Dekker, New York, 1993).

    Google Scholar 

  57. M. Misono and E. A. Lombardo (eds), Catal. Today 8 (1990) 133.

  58. R.M.G. De la Cruz, H. Falcon, M. A. Pena and J.L.G. Fierro, in preparation. (in H. Falcon, R. E. Carbonio, and J.L.G. Fierro, J. Catal. 203 (2001) 264.)

    Google Scholar 

  59. A. Slagtern and U. Olsbye, Appl. Catal., A 110 (1994) 99.

    Google Scholar 

  60. V. A. Tsipouriari and X. E. Verykios, J. Catal. 187 (1999) 85.

    Google Scholar 

  61. V. R. Choudhary, B. S. Uphade and A. A. Belhekar, J. Catal. 163 (1996) 312.

    Google Scholar 

  62. H. Provendier, C. Petit, C. Estournes, S. Libs and A. Kiennemann, Appl. Catal. A 180 (1999) 163.

    Google Scholar 

  63. M. A. Pena, J. P. Gomez and J.L.G. Fierro, Appl. Catal. A 144 (1996) 7.

    Google Scholar 

  64. H. Iwahara, T. Esaka and T. Mangahara, J. Appl. Electrochem. 18 (1988) 173.

    Google Scholar 

  65. Kagaku Binran, The Chemical Society Japan, Maruzen, Tokyo, 1993.

  66. H.F. Kay and P.C. Bailey, Acta Cryst. 10 (1957) 219.

    Google Scholar 

  67. M. Ceh, D. Kolar and L. Golic, J. Solid State Chem. 68 (1987) 68.

    Google Scholar 

  68. Denki Kagaku Binran, The Electrochemical Society Japan, Maruzen, Tokyo, 1988, p. 129.

  69. T. Hayakawa, K. Sato, T. Tsunoda, S. Hamakawa, K. Suzuki, J. Nakamura, K. Takehira and T. Uchijima, J. Chem. Soc., Chem. Commun. (1994) 1899.

  70. K. Sato, J. Nakamura, T. Uchijima, T. Hayakawa, S. Hamakawa, T. Tsunoda and K. Takehira, J. Chem. Soc., Faraday Trans. 91 (1995) 1655.

    Google Scholar 

  71. K. Sato, J. Nakamura, T. Uchijima, T. Hayakawa, T. Tsunoda and K. Takehira, Shokubai 36 (1994) 452.

    Google Scholar 

  72. K. Takehira, T. Hayakawa, S. Hamakawa, T. Tsunoda, K. Sato, J. Nakamura and T. Uchijima, Catal. Today 29 (1996) 397.

    Google Scholar 

  73. S. Hamakawa, M. Koizumi, K. Sato, J. Nakamura, T. Uchijima, K. Murata, T. Hayakawa and K. Takehira, Catal. Lett. 52 (1998) 191.

    Google Scholar 

  74. K. Sato, J. Nakamura, T. Uchijima, T. Hayakawa, S. Hamakawa, T. Tsunoda T. Shishido and K. Takehira, Solid State Ionics 136-137 (2000) 753.

    Google Scholar 

  75. S. Hamakawa, T. Hayakawa, K. Suzuki, R. Shiozaki and K. Takehira, DENKI KAGAKU 65 (1997) 1049.

    Google Scholar 

  76. F. Cavani, F. Trifiro and A. Vaccari, Catal. Today 11 (1991) 173.

    Google Scholar 

  77. UK Patent 1,442,172 (1973) to BASF AG.

  78. F. Basile, L. Basini, G. Fornasari, M. Gazzano, F. Trifiro and A. Vaccari, Chem Commun. (1996) 2435.

  79. F. Basile, G. Fornasari, F. Trifiro and A. Vaccari, Catal. Today 64 (2001) 21.

    Google Scholar 

  80. E. Ruckenstein and H.Y. Wang, Appl. Catal. A 198 (2000) 33.

    Google Scholar 

  81. U. Olsbye, D. Akporiaye, E. Rytter, M. Ronnekleiv and E. Tangstad, Appl. Catal. A 224 (2002) 39.

    Google Scholar 

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Takehira, K. Highly Dispersed and Stable Supported Metal Catalysts Prepared by Solid Phase Crystallization Method. Catalysis Surveys from Asia 6, 19–32 (2002). https://doi.org/10.1023/A:1020589132547

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