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Crystal structure and vibrational spectra of hydrazinium(2+) aquatetrafluoroindate(III), N2H6(InF4H2O)2

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Abstract

The crystal structure of hydrazinium(2+) aquatetrafluoroindate(III), N2H6(InF4H2O)2, has been determined by X-ray diffraction. The compound crystallizes in the triclinic space group \(P\bar 1\) (C i 1) with a = 6.759(2) Å, b = 6.228(1) Å, c = 5.7854(7) Å, α = 80.28(2)°, β = 88.79(1)°, γ = 69.96(2)°, V = 225.3(1) Å3, and Z = 1. The structure comprises hydrazinium(2+) cations and InF2F4/2O− anions in which In appears to be seven-coordinated in the form of a pentagonal bipyramid by four bridging fluorine atoms, two terminal fluorine atoms, and one oxygen atom. Pentagonal bipyramids are interconnected and form chains along a axis. Bands in vibrational spectra were assigned to the vibrations in N2H6 2+ cations and anionic InF2F4/2O− entities. The rather intensive band appearing at 1042 cm−1 in Raman spectrum, which is absent from infrared, is characteristic of the N2H6 2+ cation, in line with the predictions of the unit-cell group analysis for the studied system.

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References

  1. Šiftar, J.; Bukovec, P. Monatsh. Chem. 1970, 101, 1184.

    Google Scholar 

  2. Bukovec, P.; Šiftar, J. Monatsh. Chem. 1971, 102, 94.

    Google Scholar 

  3. Keppert, D.L. Prog. Inorg. Chem. 1979, 25, 41.

    Google Scholar 

  4. Christe, O.K.; Sanders, J.C.P.; Schrobilgen, G.J.; Wilson, W.W. J. Chem. Soc., Chem. Commun. 1991, 13, 837.

    Google Scholar 

  5. Christe, K.O.; Curtis, E.C.; Dixon, D.A.; Mercier, H.P.A.; Sanders, J.C.P.; Schrobilgen, G.J.; Wilson, W.W. In Inorganic Fluorine Chemistry: Toward the 21st Century: Heptacoordinated Main-Group Fluorides and Oxofluorides; Thrasher, J.S.; Strauss, S.H., Eds.; ACS Symposium Series 555; ACS: Washington, DC, 1994; pp 66–89.

    Google Scholar 

  6. Drake, G.W.; Dixon, D.A.; Sheehy, J.A.; Boatz, J.A.; Christe, K.O. J. Am. Chem. Soc. 1998, 120, 8392.

    Google Scholar 

  7. Seppelt, K. In Inorganic Fluorine Chemistry: Toward the 21st Century: Main-Group Fluorides with Coordination Numbers Greater-than-Six: Thrasher, J.S.; Strauss, S.H., Eds.; ACS Symposium Series 555; ACS: Washington, DC, 1994; pp 56–65.

    Google Scholar 

  8. Wells, A.F. Structural Inorganic Chemistry; Clarendon Press: Oxford, 1984; pp 471–474.

    Google Scholar 

  9. Bukovec, P.; Goliě, L. Acta Crystallogr. Sect. B, 1976, 32, 948.

    Google Scholar 

  10. Fisher, P.J.; Weiss, R. Acta Crystallogr., Sect. B 1973, 29, 1958.

    Google Scholar 

  11. Laval, P.J.P.; Papiernik, R.; Frit, B. Acta Crystallogr., Sect. B 1978, 34, 1070.

    Google Scholar 

  12. Hurst, H.J.; Taylor, J.C. Acta Crystallogr., Sect. B 1970, 26, 2136.

    Google Scholar 

  13. Keller, O.L. Inorg. Chem. 1963, 2(4), 783; Pausewang, V.G.; Schmitt, R.; Dehnicke, K. Z. Anorg. Allg. Chem., 1974, 408, 1.

    Google Scholar 

  14. Poojary, M.D.; Patil, K.C. Proc. Indian Acad. Sci. (Chem. Sci.) 1987, 99, 311.

    Google Scholar 

  15. Almond, P.M.; Talley, C.E.; Bean, A.C.; Peper, S.M.; Albrecht-Schmitt, T.E. J. Solid State Chem. 2000, 154, 635.

    Google Scholar 

  16. Zachariasen, W.A. Acta Crystallogr. 1954, 7, 783; Acta Crystallogr. 1954, 7, 792.

    Google Scholar 

  17. Benkiê P.; Rahten A.; Jesih A. Posvetovanja Slov. Kem. Dnevi 2000, (Pt. 1), 221.

  18. McBride, W.R.; Henry, R.A.; Skolnik, S. Anal. Chem. 1951, 23, 890.

    Google Scholar 

  19. Sedej, B. Talanta 1976, 23, 335.

    Google Scholar 

  20. Kovington, A.K. Ion-Selective Electrode Methodology; CRC Press: Florida, 1984; Vol. II, pp 76–80.

    Google Scholar 

  21. Pribil, R. Applied Complexometry; Pergamon Press: Oxford, 1982; Vol. 5; pp 121–122.

    Google Scholar 

  22. teXsan for Windows version 1.06; Crystal Structure Analysis Package: Molecular Structure Corp., 1999.

  23. Becke, A.D. J. Chem. Phys. 1993, 98, 5648.

    Google Scholar 

  24. Lee, C.; Yang, W.; Parr, R.G. Phys. Rev. B1988, 37, 785.

    Google Scholar 

  25. Frisch, M.J.; Trucks, G.W.; Schlegel, H.B.; Scuseria, G.E.; Robb, M.A.; Cheeseman, J.R.; Zakrzewski, W.G.; Montgomery, J.A.; Stratmann, R.E.; Burant, J.C.; Dapprich, S.; Millam, J.M.; Daniels, A.D.; Kudin, K.N.; Strain, M.C.; Farkas, O.; Tomasi, J.; Barone, V.; Cossi, M.; Cammi, R.; Mennucci, R.; Pomelli, C.; Adamo, C.; Clifford, S.; Ochterski, J.; Petersson, G.A.; Ayala, P.Y.; Cui, Q.; Morokuma, K.; Malick, D.K.; Rabuck, A.D.; Raghavachari, K.; Foresman, J.B.; Cioslowski, J.; Ortiz, J.V.; Stefanov, B.B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Gomperts, R.; Martin, R.L.; Fox, D.J.; Keith, T.; Al-Laham, M.A.; Peng, C.Y.; Nanayakkara, A.; Gonzalez, C.; Challacombe, M.; Gill, P.M.W.; Johnson, B.G.; Chen, W.; Wong, M.W.; Andres, J.L.; Head-Gordon, M.; Replogle, E.S.; Pople, J.A. Gaussian98, Revision A.9; Gaussian, Inc.: Pittsburgh, PA, 1998.

    Google Scholar 

  26. Cameron, T.S.; Knop, O.; Macdonald, L.A. Can. J. Chem. 1983, 61, 184.

    Google Scholar 

  27. Gillespie, R.J. Molecular Geometry; Van Nostrand Reinhold Co.: London, 1972.

    Google Scholar 

  28. Gillespie, R.J.; Hargittai I. The VSEPR Model of Molecular Geometry; Allyn and Bacon, A Division of Simon & Schuster, Inc.: Needham Heights, MA, 1991.

    Google Scholar 

  29. Christe, K.O.; Dixon, D.A.; Sanders, C.P.; Schrobilgen, G.J.; Wilson, W.W. J. Am. Chem. Soc. 1993, 115, 9461.

    Google Scholar 

  30. Christe, K.O.; Dixon, D.A.; Sanders, C.P.; Schrobilgen, G.J.; Tsai, S.S.; Wilson, W.W. Inorg. Chem. 1995, 34, 1868.

    Google Scholar 

  31. Reisfeld, M.J. Spectrochim. Acta, Part A 1973, 29, 1923.

    Google Scholar 

  32. Bukovec, P.; Orel, B.; Šiftar, J. Monatsh. Chem. 1971, 102, 885.

    Google Scholar 

  33. Keller, O.L., Jr.; Chetham-Strode, A., Jr. Inorg. Chem. 1966, 5(3), 367.

    Google Scholar 

  34. Pejov, Lj.; Petruševski, V.M.; Rahten, A.; Jesih, A.; Skapin, T. J. Mol. Struct. 2002, 604, 1.

    Google Scholar 

  35. Milićev, S.; Rahten, A.; Borrmann, H.; Šiftar, J. J. Raman Spectrosc. 1997, 28, 315.

    Google Scholar 

  36. MiliŰev, S.; Maček, J. Spectrochim. Acta Part A, 1985, 41, 55.

    Google Scholar 

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Authors and Affiliations

  1. “Jožef Stefan” Institute, Jamova 39, SI-1000, Ljubljana, Slovenia

    P. Benkič, A. Rahten & A. Jesih

  2. Institut za hemija, PMF, Arhimedova 5, PO Box 162, 1000, Skopje, Macedonia

    Lj. Pejov

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  1. P. Benkič
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  2. A. Rahten
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  3. A. Jesih
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  4. Lj. Pejov
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Correspondence to A. Jesih.

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Benkič, P., Rahten, A., Jesih, A. et al. Crystal structure and vibrational spectra of hydrazinium(2+) aquatetrafluoroindate(III), N2H6(InF4H2O)2 . Journal of Chemical Crystallography 32, 227–235 (2002). https://doi.org/10.1023/A:1020244905386

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