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Acidity characterization by microcalorimetry and relationship with reactivity

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Abstract

In the area of acid catalysis, adsorption microcalorimetry studies have allowed a significant insight in surface studies under certain experimental conditions. Consideration is given to the interpretation of the heat evolved when a basic probe molecule is adsorbed on the surface of crystalline or amorphous silica-aluminas. In particular, the number and strength of acid sites are discussed as functions of lattice structure, concentration and nature of framework cation and basicity of the probe molecules.

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Auroux, A. Acidity characterization by microcalorimetry and relationship with reactivity. Topics in Catalysis 4, 71–89 (1997). https://doi.org/10.1023/A:1019127919907

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