Abstract
Attempts in developing organozeolites, namely microporous and mesoporous crystalline inorganic-organic composites with a zeolite-like three-dimensional framework and organic moieties covalently connected to the framework, are briefly reviewed. MCM-41 type mesoporous materials modified by organic functional groups have been prepared by use of organosiloxane as a part of Si sources and by post-modification of the purely inorganic materials using organosiloxane. Also, the incorporation of organic moieties into the zeolite frameworks has been tried. Recently, several novel metal organophosphonates with a three-dimensional framework, which can be regarded as organozeolites, have been prepared. Along with these new attempts, the authors' studies in preparation, structural analysis and gas adsorption properties of microporous aluminomethylphosphonates are introduced.
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Maeda, K., Mizukami, F. Organozeolite materials and their properties. Catalysis Surveys from Asia 3, 119–126 (1999). https://doi.org/10.1023/A:1019023702312
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DOI: https://doi.org/10.1023/A:1019023702312