Abstract
The utilisation of high CO2 content natural gas, such as that found at Natuna island in Indonesia, using methane dry reforming with carbon dioxide to synthesis gas is demonstrated. Highly active catalysts employed for coke-free, stable dry reforming include alumina-supported nickel, either as-prepared or doped with tungsten oxide or calcium oxide, and the supported group VIII metals. No deactivation was observed for the duration of any of the experiments (>70 h), and the methane conversion and product distributions were close to those predicted from thermodynamic equilibrium calculations. It is calculated that the application of dry reforming to the Natuna field alone, combined with known gas-to-liquids (GTL) technology, could provide liquid fuel to Indonesia for almost 18 years.
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G.A.S. Nayoan, The Indonesian Pipeliner, January 1997.
The Natuna Gas Project, Pertamina Public Relations, Jakarta 1997.
C. Donville, Bloomberg OBG, 28 December 1992.
R.H. Crabtree, Chem. Rev. 95 (1995) 987.
V.L. Forbes, Geopolitics Energy 19 (1997) 6.
Petrominer 10(XXII) (1995) 8.
P. Leprince andM. Valais, Energy Sources 15 (1993) 95.
I. Wender, Fuel Proc. Tech. 48 (1996) 189.
M.M.G. Senden,A.D. Punt andA. Hoek, Stud. Surf. Sci. Catal. 119 (1998) 961.
C.D. Chang andA.J. Silvestri, J. Catal. 47 (1977) 249.
J.R. Rostrup-Nielsen, in: Catalysis Science and Technology, Vol. 5, eds. J.R. Andersen andM. Boudart (Springer, Berlin, 1984) p. 1.
T. Sodesawa,A. Dobash andF. Nozaki, React. Kinet. Catal. Lett. 11 (1991) 149.
J.T. Richardson andS.A. Paripatyadar, Appl. Catal. 61 (1990) 293.
N.W. Cant,R. Dumpelmann andA.M. Maitra, Stud. Surf. Sci. Catal. 107 (1997) 491.
A.T. Ashcroft,A.K. Cheetham,M.L.H. Green andP.D.F. Vernon, Nature 352 (1991) 225.
P.D.F. Vernon,M.L.H. Green,A.K. Cheetham andA.T. Ashcroft, Catal. Today 13 (1992) 417.
J. Nakamura,K. Aikawa,K. Sato andT. Uchijima, Catal. Lett. 25 (1994) 265.
A.P.E. York,J.B. Claridge,A.J. Brungs,S.C. Tsang andM.L.H. Green, J. Chem. Soc. Chem. Commun. (1997) 39.
J.B. Claridge,A.P.E. York,A.J. Brungs,C. Márquez-Alvarez,J. Sloan,S.C. Tsang andM.L.H. Green, J. Catal. 180 (1998) 85.
H. Topsøe andJ.R. Rostrup-Nielsen, Scand. J. Metallurgy 8 (1979) 168
M.C.J. Bradford andM.A. Vannice, Catal. Rev. Sci. Eng. 41 (1999) 1.
J.B. Claridge,M.L.H. Green,S.C. Tsang,A.P.E. York,A.T. Ashcroft andP.D. Battle, Catal. Lett. 22 (1993) 299.
A.M. Gadalla andB. Bower, Chem. Eng. Sci. 43 (1988) 3049.
J.B. Claridge, D.Phil. Thesis, University of Oxford (1996).
J.B. Claridge,M.L.H. Green, andS.C. Tsang, Catal. Today 21 (1994) 455. Appl. Catal. A, submitted.
M.J. Duell, unpublished report, British Gas, London Research Station, 1988.
H. Baharuddin, Developing Pacific Basin LNG Supplies, in: GASTECH’ 93, The 15th Int. LNG/LPG Conf. Exhibition, Paris, 1993.
G.A. Mills, Fuel 73 (1994) 1243.
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Suhartanto, T., York, A.P., Hanif, A. et al. Potential utilisation of Indonesia's Natuna natural gas field via methane dry reforming to synthesis gas. Catalysis Letters 71, 49–54 (2001). https://doi.org/10.1023/A:1016600223749
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DOI: https://doi.org/10.1023/A:1016600223749