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Catalytic Activity of Mesoporous Silica for Synthesis of Methyl N-Phenyl Carbamate from Dimethyl Carbonate and Aniline

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Abstract

Mesoporous silica MCM-41, especially an Al-containing one, showed high catalytic activity for synthesis of methyl N-phenyl carbamate from dimethyl carbonate and aniline at 363-383 K. It was easily separated from the product solution, and the catalyst was able to be used repeatedly.

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Authors and Affiliations

  1. Department of Materials Science, Faculty of Engineering, Tottori University, 4-101 Koyama-cho Minami, Tottori, 680-8552, Japan

    Naonobu Katada, Haruhisa Fujinaga, Yukinori Nakamura, Kazu Okumura, Kyoichi Nishigaki & Miki Niwa

Authors
  1. Naonobu Katada
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  2. Haruhisa Fujinaga
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  3. Yukinori Nakamura
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  4. Kazu Okumura
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  5. Kyoichi Nishigaki
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  6. Miki Niwa
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Katada, N., Fujinaga, H., Nakamura, Y. et al. Catalytic Activity of Mesoporous Silica for Synthesis of Methyl N-Phenyl Carbamate from Dimethyl Carbonate and Aniline. Catalysis Letters 80, 47–51 (2002). https://doi.org/10.1023/A:1015370509151

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  • DOI: https://doi.org/10.1023/A:1015370509151

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