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Mixed-Metal Oxide Phases Containing Decavanadate Clusters: Synthesis and Crystal Structures of {{(H2O)2K-μ-(H2O)3-M(H2O)3}2[V10O28] (M=Co, Ni)

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Abstract

The synthesis and structures and thermal properties of two compounds: {(H2O)2K-μ-(H2O)3-Co(H2O)3}2[V10O28] (1) and {(H2O)2K-μ-(H2O)3-Ni(H2O)3}2[V10O28] (2) are described. These compounds have been prepared by the reaction of aqueous solutions (pH=3.5) of KVO3with MCl2·6H2O (M=Co, Ni) at 70–72°C. The isomorphous structures of the two compounds consist of interlinked chains composed of arrays of {V10O28} clusters which are joined through {(H2O)2K-μ-(H2O)3-M(H2O)3} bridges. Thermogravimetric studies revealed the complete removal of all water molecules in multiple steps in the temperature range 90–208°C.

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Authors and Affiliations

  1. Department of Biological, Chemical, and Physical Sciences, Illinois Institute of Technology, Chicago, Illinois, 60616

    M. Ishaque Khan & Saadia Tabussum

  2. Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, Illinois, 60115

    Chong Zheng

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  1. M. Ishaque Khan
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  2. Saadia Tabussum
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  3. Chong Zheng
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Khan, M.I., Tabussum, S. & Zheng, C. Mixed-Metal Oxide Phases Containing Decavanadate Clusters: Synthesis and Crystal Structures of {{(H2O)2K-μ-(H2O)3-M(H2O)3}2[V10O28] (M=Co, Ni). Journal of Cluster Science 12, 583–594 (2001). https://doi.org/10.1023/A:1014298332169

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