Abstract
The local structure around Cu supported on Al2O3 was determined by UV/VIS/NIR and XAFS spectroscopic techniques. The relationship between catalytic performance for NO–CO–O2 reaction and the state of supported Cu species is discussed. A new method for estimating the fraction of aggregated to isolated Cu species is proposed.
Similar content being viewed by others
References
T. Yamamoto, T. Tanaka, R. Kuma, S. Suzuki, Y. Shimooka, Y. Kohno, T. Funabiki and S. Yoshida, Phys. Chem. Chem. Phys., submitted
T. Yamamoto, T. Tanaka, S. Suzuki, R. Kuma, T. Funabiki and S. Yoshida, Appl. Catal. A, submitted.
K. Shimizu, H. Maeshima, A. Satsuma and T. Hattori, Appl. Catal. B 18 (1998) 163.
K. Shimizu, H. Maeshima, H. Yoshida, A. Satsuma and T. Hattori, Phys. Chem. Chem. Phys. 2 (2000) 2435.
T. Tanaka, H. Yamashita, R. Tsuchitani, T. Funabiki and S. Yoshida, J. Chem. Soc. Faraday Trans. I 84 (1988) 2987.
L.-S. Kau, D.J. Spira-Solomon, J.E. Penner-Harn, K.O. Hodgson and E.I. Solomon, J. Am. Chem. Soc. 109 (1987) 6433.
N. Kosugi, H. Kondoh, H. Tajima and S. Uchida, Chem. Phys. 135 (1989) 149.
N. Kosugi, Y. Tokura, H. Takagi and S. Uchida, Phys. Rev. B 41 (1990) 131.
J.C. Bart, Adv. Catal. 34 (1986) 203.
A.F. Wells, Structural Inorganic Chemistry (Calarendon Press, Oxford, 1975).
R.F. Cooley and J.S. Reed, J. Am. Ceram. Soc. 55 (1972) 395.
F. Farges, G.E. Brown, Jr. and J.J. Rehr, Phys. Rev. B 56 (1997) 1809.
Y. Okamoto, T. Kubota, H. Gotoh, Y. Ohto, H. Aritani, T. Tanaka and S. Yoshida, J. Chem. Soc. Faraday Trans. 94 (1998) 3743.
R.M. Friedman and J. Freeman, J. Catal. 55 (1978) 10.
M.C. Marison, E. Garbowski and M. Primet, J. Chem. Soc. Faraday Trans. 86 (1990) 3027.
B.C. Lippens and J.H. de Boer, Acta Cryst. 17 (1964) 1312.
B.C. Lippens and J.J. Steggerda, Physical and Chemical Aspects of Adsorbents and Catalysts, ed. B.G. Linsen (Academic Press, London, 1970).
Y. Teraoka, C. Tai, H. Furukawa, S. Kagawa, K. Asakura and Y. Iwasawa, Shokubai 32 (1990) 426.
K.T. Jacob and C.B. Alcock, J. Am. Ceram. Soc. 58 (1975) 192.
T. Yamamoto, T. Tanaka, T. Matsuyama, T. Funabiki and S. Yoshida, J. Synchr. Rad., in press.
P.W. Park and J.S. Ledford, Appl. Catal. B 15 (1998) 221.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Yamamoto, T., Tanaka, T., Suzuki, S. et al. NO Reduction with CO in the Presence of O2 over Cu/Al2O3 (3) – Structural Analysis of Active Species by Means of XAFS and UV/VIS/NIR Spectroscopy. Topics in Catalysis 18, 113–118 (2002). https://doi.org/10.1023/A:1013897331031
Issue Date:
DOI: https://doi.org/10.1023/A:1013897331031