Abstract
The binuclear rhodium(II) complex Na2[Rh2Cl2(OAc)4]· 4H2O has an infinite sheet structure. Binuclear anionic complexes [Rh2Cl2(OAc)4]2− are bound with cationic entities. The Na+ cation has pseudooctahedral coordination and is surrounded by two chloro ligands and two oxygen atoms of bridging acetato ligands of two [Rh2Cl2(OAc)4]2− anions and two water molecules. Both Cl and H2O are bridging ligands involved in formation of the Na+ chains. The remaining water molecules are located between sheets.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
F. A. Cotton and R. A. Walton, Multiple Bonds Between Metal Atoms, Clarendon press, Oxford, 1993; E. B. Boyar and S. D. Robinson, Coord. Chem. Rev., 50, 109 (1983); T. R. Felthouse, Progr. Inorg. Chem., 29, 73 (1982).
F. P. Pruchnik, Pure Appl. Chem., 61, 795 (1989).
F. P. Pruchnik, M. Zuber, H. Pasternak and K. Wajda, Spectro-chim. Acta, 34A, 1111 (1978); F. P. Pruchnik, J. Hanuza, K. Hermanowicz, K. Wajda-Hermanowicz and M. Zuber, ibid.; 45A, 835(1989); H. Pasternak and F. P. Pruchnik, Inorg. Nucl. Chem. Lett., 12, 591 (1976); F. P. Pruchnik, A. Jezierski and E. Kalecinnska, Polyhedron, 10, 2551 (1991); T. Gøowiak, F. P.l PruchinÂik and M. Zuber, Polish J. Chem., 65, 1749 (1991).
F. P. Pruchnik, F. Robert, Y. Jeannin and S. Jeannin, Inorg. Chem., 35, 4261 (1996).
L. Natkaniec and F. P. Pruchnik, J. Chem. Soc. Dalton Trans., 5, 3261 (1994).
J. Halpern, E. Kimura, J. Molin-Case and C. S. Wong, J. Chem. Soc., Chem. Commun., 1207 (1971).
L. Trynda and F. P. Pruchnik, J. Inorg. Biochem., 58, 69 (1995); F. P. Pruchnik and D. DusÂ, J. Inorg. Biochem., vn61, 55 (1996); F. P. Pruchnik, G. Kluczewska, A. Wilczok, U. Mazurek and T. Wilczok, J. Inorg. Biochem., 65, 25 (1997); F. P. Pruchnik, M. Bien and T. Lachowicz, Metal-based Drugs, 3, 185 (1996); M. BienÂ, T. M. Lachowicz, A. Rybka, F. P. Pruchnik and L. Trynda, Metal-Based Drugs, 4, 81 (1997); (g) L. Trynda-Lemiesz and F. P. Pruchnik, J. Inorg. Biochem., 66, 187 (1997).
H. Pasternak, E. Lancman and F. P. Pruchnik, J. Mol. Catal., 29, 13 (1985); H. Pasternak, F. P. Pruchnik, K. Wajda-Hermanowicz and M. Zuber, Polish J. Chem., 63, 619 (1986); H. Pasternak and F. P. Pruchnik, ibid., 66, 865 (1992).
M. P. Doyle in I. Ojima, (Ed.) Catalytic Asymmetric Synthesis, VCH Publishers, New York, 1993, ch 3; M. P. Doyle, M. N. Protopopova, Q.-L. Zhou and J. W. Bode, Tetrahedron Asymme-try, 6, 2157 (1995).
J. L. Bear, H. B. Gray Jr., L. Rainen, I. M. Chang, R. Howard, G. Serio and A. P. Kimball, Cancer Chemother. Rep. 59, 611 (1975); R. A. Howard, A. P. Kimball and J. L. Bear, Cancer Res., 39, 2568 (1979).
C. A. Crawford, J. H. Matonic, J. C. Huffman, K. Folting, K. R. Dunbar and G. Christou, Inorg. Chem., 36, 2361 (1997); K. V. Catalan, D. J. Mindiola, D. L. Ward and K. R. Dunbar, Inorg. Chem., 36, 2458 (1997); K. R. Dunbar, J. H. Matonic, V. P. Saharan, C. A. Crawford and G. Christou, J. Am. Chem. Soc., 116, 2201 (1994).
R. G. Hughes, J. L. Bear and A. P. Kimball, Proc. Am. Assoc. Cancer Res., 13, 120 (1972).
P. N. Rao, M. L. Smith, S. Pathak, R. A. Howard and J. L. Bear, J. Nat. Cancer Inst., 64, 905 (1980).
L. M. Hall, R. J. Speer, H. J. Ridgway, J. Clin. Hematol. Oncol., 10, 25 (1980).
E. Tselepi-Kalouli, N. Katsaros, J. Inorg. Biochem., 40, 95 (1990).
A. R. Chakravarty, F. A. Cotton, D. A. Tocher and J. H. Tocher, Organometalics, 4, 8 (1985); F. Barcelo, F. A. Cotton, P. Lahuerta, R. Llusar, M. Sanau, W. Schwotzer and M. A. Ubeda, Organo-metalics, 5, 808(1986); F. Estevan, G. Gonzalez, P. Lahuerta, M. Martinez, E. Peris and R. van Eldik, J. Chem. Soc. Dalton Trans., 1045 (1996); G. Gonzalez, M. Martinez, F. Estevan, A. Garcia-Bernabe, P. Lahuerta, E. Peris, M. A. Ubeda, M. R. Diaz, S. Garcia-Granda and B. Tejerina, New J. Chem., 20, 83 (1996); F. Estevan, S. Garcia-Granda, P. Lahuerta, J. Latorre, E. Peris and M. Sanau, Inorg. Chim. Acta, 229, 365 (1995).
G. A. Rempel, P. Legzdins, H. Smith and G. Wilkinson, Inorg. Synth., 13, 90 (1972).
B. A. Frenz, SDP-Structure Determination Package, Enraf-Nonius; Delft, 1987.
A. C. T. North, D. C. Phillips and F. S. Mathews, Acta Crystallogr., A24, 351 (1968).
G. M. Sheldrick, SHELXTL PC, Version 4.2. An Integrated system for solving, refining and displaying crystal structures from diffraction data; Siemens Analytical X-Ray Instruments, INC.; Madison, WI, 1990.
I. Vickovič, J. Appl. Cryst., 21, 987 (1988).
V. M. Miskowski, W. P. Schaefer, B. Sadeghi, B. D. Santarsiero and H. B. Gray, Inorg. Chem., 23, 1154 (1984).
L. M. Dikareva, G. G. Sadikov, I. B. Baranovskii and M. A. Porai-Koshits, Zh. Neorg. Khim., 25, 3146 (1980).
V. M. Miskowski, R. F. Dalllinger, G. G. Christoph, D. E. Morris, G. H. Spies and W. H. Woodruff, Inorg. Chem., 26, 2127 (1987).
Z.-H. Zhou, R. J. Wang, T. C. W. Mak and C.-M. Che, Inorg. Chim. Acta, 180, 1 (1991).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Gałdecka, E., Gałdecki, Z., Pruchnik, F.P. et al. Infinite sheet structure of disodium tetra-μ-acetato- dichlorodirhodate(II) tetrahydrate. Transition Metal Chemistry 24, 100–103 (1999). https://doi.org/10.1023/A:1006941000717
Issue Date:
DOI: https://doi.org/10.1023/A:1006941000717