Abstract
The environmental chemistry of beryllium (Be) was investigated at the Lysina catchment in western Bohemia, Czech Republic, a forest ecosystem with high loadings of acidic atmospheric deposition. The catchment supports Norway spruce plantations; it is underlain by leucogranite and the soils are Spodosols. Average concentrations of Be were high in groundwater (3.3 µg L-1) and in stream water (1.5 µg L-1), in comparison to the drinking water standard of the Czech Republic (0.2 µg L-1). Chemical equilibrium calculations suggest that aquoberyllium Be2+ was the prevailing inorganic species in drainage waters at the site. Atmospheric deposition of Be (45 µg m-2 yr-1) was small in comparison to drainage outflow (586 µg m-2 yr-1) at Lysina. Elevated Be concentrations in drainage water appear to be the result of the mobilization of Be from soils and weathered bedrock due to acidic atmospheric deposition. Increased mobility of Be due to acidification may have serious ecological consequences in acid-sensitive areas with terrestrial pools of available Be.
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Anonymous: 1992, ČSN 73 6053, Vydavatelství Norem, Prague.
Baes Jr., C.F. and Mesmer, R.E.: 1976, The Hydrolysis of Cations, John Wiley and Sons, New York.
Bouška, V. and Pešek, I.: 1997, Distribution of Sulfur and Arsenic in Coal of the Sokolov Basin, Research Report, Charles University, Prague (in Czech).
Breiter, K.: 1988, Silicate Analyses-Database, Czech Geological Survey, Prague.
Breiter, K.: 1996, “Granites of the Slavkov Forest,” in Conference Proceedings: Mining Past and Future of the Slavkov Forest. Okresni Muzeum Sokolov, Sokolov, Czech Republic, pp. 25–44 (in Czech).
Buzek, F., Hruška, J. and Krám, P.: 1995, Water, Air, Soil Pollut. 79, 391.
Klein, C., and Hurlbut, Jr, C.S.: 1985, Manual of Mineralogy after J.D. Dana, 20th Edition, John Wiley and Sons, New York.
Krám, P. and Hruška, J.: 1994, Appl. Hydrogeol. 2/94, 50.
Krám, P., Hruška, J., Driscoll, C.T. and Johnson, C.E.: 1995, Water, Air, Soil Pollut. 85, 1831.
Krám, P., Hruška, J., Wenner, B.S., Driscoll, C.T. and Johnson, C.E.: 1997, Biogeochemistry 37, 173.
Kubizňáková, J.: 1987a, “Behavior of Beryllium in the Sokolov District”, in B. Moldan and T. Pačes (eds.), GEOMON Extended Abstracts, Czech Geol. Survey, Prague, pp. 188–190.
Kubizňáková, J.: 1987b, Water, Air, Soil Pollut. 34, 363.
Martin, R.B.: 1986, “Bioinorganic Chemistry of Metal Ion Toxicity”, in H. Sigel (ed.), Metal Ions in Biological Systems, Vol. 20, Concept on Metal Ion Toxicity, Marcel Dekker, New York.
Moldan, B. and Schnoor, J.L.: 1992, Environ. Sci. Technol. 26, 14.
Moore, J.W.: 1991, “Beryllium”, in Inorganic Contaminants of Surface Water Research and Monitoring Priorities, Springer Series on Environmental Management, Springer-Verlag, New York, pp. 50–56.
Panzer, R.E.: 1985, “Beryllium, Magnesium, Calcium, Strontium, Barium, and Radium”, in A.J. Bard, R. Parsons and J. Jordan (eds.), Standard Potentials in Aqueous Solutions, Int. Union Pure Appl. Chem., Marcel Dekker, New York, pp. 675–686.
Pontius, F.W.: 1993, Am. Water Works Assoc. J. 85, 42.
Sehecher, W.D. and McAvoy, D.C.: 1991, MINEQL': A Chemical Equilibrium Program for Personal Computers-User's Manual, Version 2.1., Environ. Res. Software, Edgewater, Maryland.
Veselý, J.: 1994, “Effects of Acidification on Trace Metal Transport in Fresh Waters”, in C.E.W. Steinberg and R.F. Wright (eds.), Acidification of Freshwater Ecosystems, John Wiley & Sons, Chichester, pp. 141–151.
Veselý, J., P. Beneš, and K. Ševčík: 1989, Water Res. 23, 711.
Wong, C.Y., and J.D. Woolins: 1994, Coord. Chem. Rev., 130, 243.
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Krám, P., Hruška, J. & Driscoll, C. Beryllium Chemistry in the Lysina Catchment, Czech Republic. Water, Air, & Soil Pollution 105, 409–415 (1998). https://doi.org/10.1023/A:1005091728272
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DOI: https://doi.org/10.1023/A:1005091728272