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A model for diffusion-controlled solidification of ternary alloys in mushy layers

Published online by Cambridge University Press:  20 May 2003

D. M. ANDERSON
Affiliation:
Department of Mathematical Sciences, George Mason University, Fairfax, VA 22030, USA

Abstract

We describe a model for non-convecting diffusion-controlled solidification of a ternary (three-component) alloy cooled from below at a planar boundary. The modelling extends previous theory for binary alloy solidification by including a conservation equation for the additional solute componentand coupling the conservation equations for heat and species toequilibrium relations from the ternary phase diagram. We focus on growth conditions under which the solidification path (liquid line of descent) through the ternary phase diagram gives rise to two distinct mushy layers. A primary mushy layer, which corresponds to solidification along aliquidus surface in the ternary phase diagram, forms above a secondary (or cotectic) mushy layer, which corresponds to solidification along acotectic line in the ternary phase diagram. These two mushy layers are bounded above by a liquid layer and below by a eutectic solid layer. We obtain a one-dimensional similarity solution and investigate numerically the role of the control parameters in the growth characteristics. In the special case of zero solute diffusion and zero latent heat ananalytical solution can be obtained. We compare our predictions with previous experimental results and with theoretical results from a related model based on global conservation laws described in the Appendix. Finally, we discuss the potentially rich convective behaviour anticipated for other growth conditions.

Type
Research Article
Copyright
© 2003 Cambridge University Press

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Footnotes

With an Appendix by A. F. Thompson, H. E. Huppert & M. G. Worster.