Reaction de l'oxygene avec les alcoolates de cuivre I.

https://doi.org/10.1016/S0040-4039(01)81448-9Get rights and content

Abstract

Copper (I) alkoxides are oxidized by molecular oxygen in acetonitrile to carbonyl compounds ; a mechanism involving Cu(III) intermediates is proposed.

Références (19)

  • W.G. Nigh
  • M. Munakata et al.

    J. Chem. Soc. Chem. Comm.

    (1980)
  • H. Gampp et al.

    J. of Molec. Cat.

    (1980)
  • G.R. Dyrkacz et al.

    J. Am. Chem. Soc.

    (1976)
  • C.A. Owen
  • G.M. Whitesides et al.

    J. Am. Chem. Soc.

    (1974)
  • R.A. Sheldon et al.R.A. Sheldon et al.
  • G. Sosnovsky et al.
  • W. Brackman et al.

    Rec. Tr. Ch. Pays-Bas

    (1966)
    W. Brackman et al.

    Rec. Tr. Ch. Pays-Bas

    (1966)
There are more references available in the full text version of this article.

Cited by (21)

  • TEMPO-mediated aerobic oxidation of alcohols using copper(II) complex of bis(phenol) di-amine ligand as biomimetic model for Galactose oxidase enzyme

    2016, Polyhedron
    Citation Excerpt :

    In 1977, for the first time, a ligand-assisted Cu catalytic system comprising copper with pyridine (py) or bipyridine (bipy) ligands [23] was reported to catalyze the selective oxidation of alcohols to aldehydes using O2 as final oxidant. A few decades later, the catalytic activity of other N-containing ligands such as 1,10-phenanthroline (phen) or TMEDA-assisted Cu systems was re-investigated [24]. The catalytic oxidation of alcohols to aldehydes based on the isolated Cu complexes has been also reported by several groups [25–28].

View all citing articles on Scopus
View full text