Reaction de l'oxygene avec les alcoolates de cuivre I.
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2016, PolyhedronCitation Excerpt :In 1977, for the first time, a ligand-assisted Cu catalytic system comprising copper with pyridine (py) or bipyridine (bipy) ligands [23] was reported to catalyze the selective oxidation of alcohols to aldehydes using O2 as final oxidant. A few decades later, the catalytic activity of other N-containing ligands such as 1,10-phenanthroline (phen) or TMEDA-assisted Cu systems was re-investigated [24]. The catalytic oxidation of alcohols to aldehydes based on the isolated Cu complexes has been also reported by several groups [25–28].
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