Nickel(II)–aryl complexes as catalysts for the Suzuki cross-coupling reaction of chloroarenes and arylboronic acids
Graphical abstract
A general catalytic system involving Ni(PPh3)2(1-naph)Cl and PPh3 proved to be highly effective for the Suzuki reaction of aryl chlorides under mild conditions.
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Acknowledgments
The authors thank the National 863 Program of China (Z36-1-715-98) and the National Natural Science Foundation of China (Project No. 20672116) for financial support of this work.
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2015, Journal of Molecular Catalysis A: ChemicalNickel-catalysed Suzuki-Miyaura cross-coupling reactions of aryl halides with arylboronic acids in ionic liquids
2015, Catalysis CommunicationsCitation Excerpt :Due to high sensitivity to air and moisture, the catalytically active Ni (0) complexes are often generated by Ni (II) complexes via in situ reactions [9]. Since Miyaura and co-workers reported the first nickel-catalysed Suzuki–Miyaura reactions of aryl halides and arylboronic acids [10], additional successful examples have been reported by Indolese [11], Genet [12], Miyaura and Inada [13], Percec [14–16], Hu [17], Shi [18], Garg [19], Yang [20,21], Han [22–24], Wang [25] and Valente [26]. In spite of the significant progress that has been obtained, it is still necessary to develop a more efficient catalytic system for transition metal catalysed Suzuki–Miyaura reactions under mild conditions.