Ultrapotassic dykes in the Moldanubian Zone and their significance for understanding of the post-collisional mantle dynamics during Variscan orogeny in the Bohemian Massif
Graphical abstract
Introduction
The Moldanubian Zone of the Bohemian Massif (Fig. 1) is known for the presence of ultrapotassic igneous (Foley et al., 1987) rocks that form plutons of Mg-K syenite (durbachite) and dykes of vaugnerite, minette, syenite porphyry, kersantite, lamproites (Holub, 1997, Krmíček et al., 2011). This K-rich magmatism is considered as an indicator of evolving mantle dynamics that occurred along the European Variscan orogenic belt (Fig. 1a, Abdelfadil et al., 2014, Couzinié et al., 2014, Finger et al., 2007, Gerdes et al., 2003, Janoušek and Holub, 2007, Krmíček et al., 2016, Štemprok et al., 2014, von Raumer et al., 2013, Zeitlhofer et al., 2016). In the Moldanubian Zone of the Bohemian Massif, the ultrapotassic rocks occur mostly along two NNE–SSW-orientated belts (Fig. 1b) and the origin of their formation is the subject of controversy. According to Janoušek and Holub (2007), the ultrapotassic magma derived from anomalous mantle sources contaminated by crustal material and their formation was related to subduction of the Saxothuringian plate beneath the Teplá-Barrandian Block (the Teplá suture in Fig. 1a) and it was coeval with the granulite facies metamorphism in the Moldanubian Zone (Schulmann et al., 2014). Relations of lamproites dykes and ultrapotassic plutons in the Moldanubian Zone to the subduction of Rhenohercynian oceanic basin (Rhenohercynian suture in Fig. 1a) are assumed by Kroner and Romer (2013) and Krmíček et al. (2016). According to von Raumer et al. (2014), the ultrapotassic rocks along the whole Variscan orogeny (Eastern Alps, Alpine External Massifs with those of Corsica, the French Central Massif, Black Forest, Vosges and the Bohemian Massif, Fig. 1a) were created by slab windows and/or the sinking of the subducted Rhenohecynian slab into the mantle. Available geochronological dating shows wide range of ages of this magmatism that includes ages of 293–343 Ma from the Bohemina Massif (Holub et al., 1997, Kusiak et al., 2010, Verner et al., 2008, von Seckendorf et al., 2004), 305 Ma from vaugnerite in the French Central Massif (Couzinié et al., 2014) and 265 Ma from lamprophyre in the Central Iberian Zone (Scarrow et al., 2011). Based on recent results of petrological study (Faryad et al., 2013, Faryad et al., 2015), the main processes of metamorphism and formation of igneous rocks in the Moldanubian Zone were operated by subduction and subsequent collision of the Moldanubian plate beneath the Teplá-Barrandian Block (the Moldanubian suture in Fig. 1a).
In this work, we present detailed petrology, geochemistry and age data of two dykes of vaugnerite and syenite porphyry that occur within migmatized gneisses of the Monotonous unit in the Moldanubian Zone. Field relations show that the vaugnerite dyke is relatively older than the syenite porphyry but both cross cut the older granite apophyses which follow metamorphic fabrics in the gneisses and are parallel to the SSW–NNE directed Central Bohemian Plutonic Complex (Fig. 1b). By combination of mineral textures and compositional variations in minerals and bulk rock chemistry we attempt to clarify the origin and source of the ultrapotassic magma and analyse subsequent processes of its fractionation and assimilation with crustal material during magma ascendance. The results of this work are used to discuss the relations of ultrapotassic magmatism to mantle dynamics during post-subduction history and granulite facies metamorphism in the Moldanubian Zone.
Section snippets
Geological setting
The Bohemian Massif, representing the easternmost segment of the European Variscides, is formed by two crustal blocks (the Brunovistulian and the Teplá-Barrandian, Fig. 1) and two zones (the Moldanubian and the Saxothuringian) with various rocks affected by degrees of metamorphism and deformation. The Saxothuringian Zone occupies the northern part of the Bohemian Massif, while the Moldanubian Zone is located in the southern part of the Bohemian Massif between the Teplá-Barrandian Block in the
Analytical methods
Chemical analyses were obtained with the JEOL JXA-8530F microprobe equipped with wavelength- and energy-dispersive spectrometers (WDS and EDS) at the Department of Petrology and Structural Geology, Charles University in Prague. The operating conditions were 15 kV with and 30 nA beam current for spot analyses and 20 kV and 120 nA for element mappings. Standards were quartz (Si), corundum (Al), periclase (Mg), magnetite (Fe), rhodonite (Mn), calcite (Ca), rutile (Ti), chromium oxide (Cr), vanadinite
Petrology and mineral chemistry
The vaugnerite and syenite porphyry were sampled across the dyke from center to contact with the host rock. In total, 4 samples of vaugnerite, 5 samples of syenite porphyry and two enclaves in the syenite porphyry were taken for detailed study.
Major and trace element geochemistry
The whole-rock geochemical data (Table 2) indicates that all analysed samples are ultrapotassic (according to definition of Foley et al. (1987), K2O > 5.8 wt.%, K2O/Na2O > 2.2 and MgO > 3.52 wt.%). Based on the K2O + Na2O:SiO2 ratios (Le Bas et al., 1986) the vaugnerite plots in the field of basaltic trachyandesite, while enclaves and syenite porphyry in the fields of trachyandesite and trachyte, respectively (Fig. 6a). All rock samples are metaluminious (by alumina saturation of Shand (1927) and have a
U/Pb dating of vaugnerite
Nine single-grain analyses of titanite from the vaugnerite sample (LR782) yielded relatively radiogenic Pb isotopic data, with modest amounts of common Pb (Table 3, Table 4, Fig. 9a, b). Titanite grains were dissolved in two exploratory batches. Of the four grains initially dissolved, two were translucent, honey coloured (s1–s2), while two were more turbid and brown (s3–s4). Isotopic results from s3 and s4 showed greater dispersion relative to s1 and s2 (Fig. 9a), thus the five crystals
Mineral textures and crystallization history of the vaugnerite and syenite porphyry dykes
Mineral textures in the vaugnerite indicate at least two stages of crystallization that occurred under different P-T-X conditions (Fig. 10). The oval-shaped pseudomorphs with orthorhombic contours, which are formed of talc with relatively high nickel content, support their formation after olivine. Equilibrium phases of this early stage of crystallization were olivine, apatite, biotite (type I) and clinopyroxene. This is consistent with the result of melting experiments of Parat et al. (2010) on
Conclusions
The mineral chemistry and bulk rock major and trace element concentrations in vaugnerite and syenite porphyry dykes demonstrate that their source magma was formed by very low-degrees of partial mantle melting. The primary minerals in the rocks are phlogopite, clinopyroxene, apatite, chromium-rich spinel and pseudomorphs of talc after olivine. The presence of F-rich apatite and phlogopite with carbonate suggest high concentration of F, H2O and CO2 in the source magma. The melting process likely
Acknowledgments
This work was supported by the Czech Science Foundation (research project number 13-06958S). The authors thank M. Racek and R. Jedlička for their help with microprobe analyses. We thank A. Fabbrizio for discussion during manuscript preparation. We are grateful to S. Couzinié and L. Krmíček for detailed reviews which helped us to considerably improve the manuscript. N. Eby is thanked for his editorial handling.
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