Correlation of heavy metal binding capacity of thiol-SAMMS using the Misono softness parameter

doi:10.1016/j.inoche.2005.09.028

Inorganic Chemistry Communications

Volume 9, Issue 1, January 2006, Pages 96-98

https://doi.org/10.1016/j.inoche.2005.09.028 Get rights and content

Abstract

The binding chemistry of heavy metal cations to a thiolated nanoporous solid-phase sorbent is correlated with the Misono softness parameter, allowing for useful prediction of binding capacity.

Graphical abstract

Two unprecedented types of ligands with C2 symmetry, with comparable essential features, are proposed as supports for metal centres in bimetallic promotion of organic syntheses. Preparation and characterization of bis-chelating bipyridine ligands A and X-ray analysis of a related palladium binuclear complex are described. Synthesis and characterization of a dialdehyde intermediate for type B ligands are also reported.

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Acknowledgements

Pacific Northwest National Laboratory is operated for US Department of Energy (DOE) under contract DE-AC0676RLO1830 by Battelle Memorial Institute. This work was supported by the Laboratory Directed Research and Development Program.

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Correlation of heavy metal binding capacity of thiol-SAMMS using the Misono softness parameter

Abstract

Graphical abstract

Section snippets

Acknowledgements

Stud. Surf. Sci. Catal.

Micropor. Mesopor. Mater.

J. Inorg. Nucl. Chem.

J. Am. Chem. Soc.

Science

Science

Env. Sci. Technol.

J. Am. Chem. Soc.

Ind. Eng. Chem. Res.