Structural data of structure variation and luminescence of 3D, 2D and 1D lanthanide coordination polymers with 1,3-adamantanediacetic acid

In this data article, we report the structure, Fourier transform infrared spectroscopy(FT-IR), powder X-ray diffraction (PARD), luminescence decay, thermogravimetric analysis (TGA) and UV–vis data of three series Ln-MOFs. Detailed structure and luminescence properties were discussed in our previous study (Zhao et al., 2018) [1]. The data includes the structure patterns of ligand H2ADA, FT-IR, PXRD and thermostability of Ln-MOFs in the air, detailed structure information for these structures are listed in Table 1, Table 2, Table 3, Table 4, Table 5, Table 6, Table 7.

In this data article, we report the structure, Fourier transform infrared spectroscopy(FT-IR), powder X-ray diffraction (PARD), luminescence decay, thermogravimetric analysis (TGA) and UVvis data of three series Ln-MOFs. Detailed structure and luminescence properties were discussed in our previous study (Zhao et al., 2018) [1]. The data includes the structure patterns of ligand H 2 ADA, FT-IR, PXRD and thermostability of Ln-MOFs in the air, detailed structure information for these structures are listed in Table 1

Experimental design, materials, and methods
Synthesis of 1a: In a 250 mL Teflon-lined stainless-steel autoclave, 0.396 mmol H 2 ADA, 0.594 mmol Tb(NO 3 ) 3 Á 6H 2 O and 0.396 mmol 1,10-phenanthroline (phen) were mixed, then 100 mL H 2 O added, and mixed by a magnetic stirrer. The reactants were sealed in the Teflon-lined stainless-steel autoclave and heated at 418 K for 6 days.
Synthesis of 2a-2c: In a 50 mL beaker, 0.396 mmol H 2 ADA and 20 mL H 2 O were mixed, and the pH adjusted to 6 with 0.1 M NaOH solution. Then the solution was mixed with 20 mL MeOH solution containing 0.27 mmol Ln(NO 3 ) 3 Á 6H 2 O. After that, 0.269 mmol dmp dissolved in 20 mL EtOH solution was added to the mixture. Then it was transferred to a bottle and sealed, allowing the reaction to proceed at 333 K for 72 h.
Synthesis of 3a-3c: In a 100 mL bottle, 0.396 mmol H 2 ADA was mixed with 0.13 mmol Ln (NO 3 ) 3 Á 6H 2 O. 10 mL DMF and 50 mL H 2 O was added and stirred for 10 min. Then the bottle was sealed and reacted at 333 K for 72 h. Table 4 Selected bond lengths and bond angles of 2c.
Single crystal X-ray diffraction data was collected on a Bruker SMART 1000 CCD, with Mo-Ka radiation (Wavelength ¼ 0.71073 Å) at room temperature. The structure was refined by full-matrix least-squares methods with SHELXL-97 module. FT-IR was obtained in KBr pellets and recorded on a Nicolet 330 FT-IR spectrometer. TGA was recorded on a Netzsch-Bruker TG-209 unit in the air atmosphere. Luminescence spectra and lifetimes were recorded on an Edinburgh FLS980 at room temperature. Phase purity of bulk sample was determined on a DMAX2200VPC diffractometer, at 30 kV and 30 mA. Table 5 Selected bond lengths and bond angles of 3a.