Elsevier

Desalination

Volume 404, 17 February 2017, Pages 182-191
Desalination

Desalination of salty water using vacuum spray dryer driven by solar energy

https://doi.org/10.1016/j.desal.2016.11.015Get rights and content

Highlights

  • Theoretical analysis for desalination under reduced pressure aided by solar energy,

  • New approach and design for a solar-aided desalination system under reduced pressure,

  • New approach and design for solar energy collector using spherical-shaped system,

  • Recycled latent heat of evaporation, waste heat from the vacuum pump, heat collected from the solar panels and droplet colour were considered in the theoretical analysis.

Abstract

This paper addresses evaporation under vacuum condition with the aid from solar energy and the recovered waste heat from the vacuum pump. It is a preliminary attempt to design an innovative solar-based evaporation system under vacuum. The design details, equipment required, theoretical background and work methodology are covered in this article. Theoretically, based on the energy provided by the sun during the day, the production rate of pure water can be around 15 kg/m2/day. Assumptions were made for the worst case scenario where only 30% of the latent heat of evaporation is recycled and the ability of the dark droplet to absorb sun energy is around 50%. Both the waste heat from the pump and the heat collected from the photovoltaic (PV) panels are proposed to raise the temperature of the inlet water to the system to its boiling point at the selected reduced pressure.

Introduction

Water and energy are fundamental necessities for life on Earth and to sustain the modern world. In many parts of the world, the control and exploitation of water and energy has driven economic development. In many other places there are shortages in fresh water and energy supplies. Drinking water of acceptable quality has become a scarce commodity not to mention unevenly distributed geographically worldwide [14], [24]. The World Health Organization (WHO) has estimated that lack access to drinking water may be an issue for more than a billion people [15]. The vast majority of these people are from undeveloped countries and/or living in rural areas where there is low population density. In remote locations it is very difficult and costly to install conventional clean water solutions, [25]. In many countries where there are shortages of clean and fresh water, there are many other water resources that have potential to be transformed. Such resources seawater, brackish/saline or contaminated groundwater, and coal seam gas water [26]. These kinds of water require an innovative technique of treatment that uses sustainable and low cost energy to produce clean water.

Desalination of saline water is known to be one of the most sustainable alternative solutions to provide fresh water. This resource can play a significant role in socioeconomic development in many developing countries such as Africa, Pacific Asia and countries in the Middle East [16] and Latin America. Desalination is a process in which saline water is separated into two parts: one that has a low concentration of dissolved salts (fresh water), and the other which has a much higher concentration of dissolved salts than the original feed water (brine concentrate), [27]. Reverse Osmosis (RO), a conventional desalination technology, produces brine (70–55% of intake flow) depending of feed water quality; the dissolved salt concentration of the brine varies from 50 to 75 g/L resulting in a much higher density than seawater (Hamawand et al., 2013). Desalination of salty water/seawater is expensive, mostly because of the energy required [17]. However, desalination is a growing field around the world where the needs for drinkable water are crucial [2]. All conventional seawater desalination techniques such as RO, thermal distillation such as multi stage flash (MSF), electro-dialysis, or their combinations consume a large amount of energy and they do not recover the salt eventually. These techniques may also cause air pollution due to the large consumption of energy derived from fossil fuels [19], [20]. Furthermore, the brine remains from these processes are huge and represent another potential environmental problem [18]. There is a potential for using algae to clean the water after amending it with some chemicals, however this has not been carried out experimentally [11]. Therefore, the utilization of renewable energy can be considered as one of energy sources of seawater desalination [3], [5], [17].

A complete separation of salt from salty water is something that cannot be achieved by many of the conventional methods. One conventional, most efficient and reliable method for complete separation is evaporation. Evaporation of water at atmospheric pressure requires large amounts of energy to raise the water temperature to the boiling point. In addition, at atmospheric pressure the evaporation rate is slow unless more vigorous heat is supplied. This problem can be overcome by carrying out the evaporation under reduced pressure where water can be evaporated at temperatures below its atmospheric pressure boiling point. Water evaporation under reduced pressure is energy efficient according to the laws of thermodynamics, and can be driven by low-grade thermal energy sources such as solar heat or process waste heat. While the evaporation under reduced pressure will accelerate the evaporation rate, one must be concerned with potential freezing problems [4]. Heat is required for water droplets to evaporate, heat is provided from the surrounding. Without supplemental heat there is a risk that the equipment parts get chilled and the remaining droplets freeze [1]. Carey et al. [21] conducted experiments under contract to NASA related to evaporation of water under vacuum. The set up consisted of 0.6 m3 environmental vacuum chamber and a 250 mL beaker with 25 mL of liquid water at a temperature of 20 °C. The liquid took approximately 150 min to evaporate under reduced pressure of 0.38 kPa. In this experiment no external heat was provided neither to the liquid or the chamber.

Valuable information on desalination of seawater using solar energy has been reported, however, the desalination of sea water using vacuum spray dryer has not been fully elucidated. This study presents an innovative design for evaporation of water using renewable energy from the sun and recycles the latent heat of evaporation. Also the waste heat from the pumps and collected heat from PV panels that provide the pump with electricity are suggested as another source of energy [7], [8].

Section snippets

Theory

Water such as concentrated salty water produced from other desalination processes such as RO process, brackish/saline groundwater and/or seawater can be sprayed inside a double walled glass column (evaporation column) exposed to sun light, Fig. 1. The double walled column will retain the heat inside the column and allow a full exposure to sun light. The column will be operated under reduced pressure to lower the water boiling point temperature. The generated vapour will condense on the chilled

Mathematical model

When a free water surface is in contact with pure vapour, the equilibrium rate of molecule transfer from vapour phase to the liquid or from the liquid phase to the vapour is given by kinetic theory of gases. When the system is not at equilibrium, the net rate of evaporation or condensation per unit droplet surface area is governed by modified Hertz-Knudsen equation [10], [28], first proposed by Alty 1931 [29]. Maa [29], studied the evaporation rate of different solvents including water. This

Simple scenario

Assume low vacuum pressure of 6.9 KPa, this means that the droplet needs to enter the system at 38.7 °C to start evaporating instantly (no initial condensation).

The maximum amount of energy received from the sun in ideal circumstances is 1000 W/m2. Fig. 3 shows the energy received from the sun per square meter on a clear day. The energy varies between 100 and 1000 W/m2 depending on time of day. The data for the actual energy received which is provided by the sun on a clear day was retrieved from a

Methodology

The experimental evaluation will be carried out as following;

  • Empty column evaluation: estimate the heat accumulation in a one square meter area system with time.

  • The water can be heated to a variety of temperatures prior to spreading in the spray column; this will help to indicate the optimum temperature of the water and at the same time help to evaluate the efficiency of using the waste heat from the vacuum pump.

  • The variables that should be considered in regards to the droplet will be: size,

Other design option

The other design option is a rotating black coloured conveyer where the droplet sprayed over and travels instead of traveling in the vacuum (mostly vapour). In this case the entire surface will collect the energy from the sun and will be transferred to the droplet by conduction. The droplet will travel from one end of the conveyer to the other end where the dry salt can be collected by scrapping (Fig. 8).

Innovative system for harvesting solar energy

Another option for the design of the system is a spherical closed environment. This system can be used to trap the sun light inside the system. In case the system used for evaporation, mirrors attached to the inside of the spherical shaped system (Fig. 9) are capable of reflecting the energy without losing it for more efficient energy collection and more efficient evaporation.

In case the spherical system is used for collecting heat and electricity, the system should covered with PV cells, this

Conclusions

To conclude, the innovative approach and design presented in this article shows a promising potential of more efficient use of solar desalination when combined with vacuum action and waste heat/latent heat/solar heat recycling. PV cells can be used to drive the vacuum pump in the system. Around 15 kg/m2/day of pure water can be produced in addition to by-product salt. Spherical closed system that is capable of trapping sun light will have a better efficiency than an open design to collect the

Acknowledgement

The authors would like to thank Professor David Buttsworth (USQ/Australia) for his valuable advice and help to achieve this work.

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