Elsevier

Synthetic Metals

Volume 86, Issues 1–3, 28 February 1997, Pages 2195-2196
Synthetic Metals

Effect of anion and isotope substitution on physical properties of organic metals series ET2[Hg(SCN)3-nXn], where X=Cl,Br,I; n=1,2

https://doi.org/10.1016/S0379-6779(97)81093-4Get rights and content

Abstract

A significant effect of the anion and isotope substitution on ESR parameters of the titled family is described. These compounds form a class of similar metal-like salts with κ-type packing of ET molecules and polymeric anions. The deuterated chlorine containing salt reveals the β-structure of ET sheets. The differences in temperature dependencies of ESR parameters for these salts are attributed to the peculiarities of the dimerized cationic sheets and the modification of SCN and halogen functioning in anion composition.

References (6)

  • M.Z. Aldoshina et al.

    Synth. Met.

    (1993)
  • E.I. Yudanova et al.

    Synth. Met.

    (1994)
  • E.I. Yudanova et al.

    Synth. Met.

    (1995)
There are more references available in the full text version of this article.
View full text
Copyright © 1997 Published by Elsevier B.V.