Elsevier

Synthetic Metals

Volume 85, Issues 1–3, 15 March 1997, Pages 1677-1678
Synthetic Metals

A new family of hybrid materials formed by TTF layers and oxalato-bridged bimetallic magnetic clusters.

https://doi.org/10.1016/S0379-6779(97)80394-3Get rights and content

Abstract

An extensive family of organic/inorganic materials formed by TTF and oxalato-bridged bimetallic clusters is reported. These hybrid molecular materials, formulated as (TTF)4MII(H2O)2[MIII(ox)3]2.nH2O (MIII = Cr and Fe; MII = Mn, Fe, Co, Ni, Cu and Zn), show layers of oxalato-bridged MIII]-M[suII-MIII turners alternating with layers of TTF+ cations presenting, for the first time, a 1-D κlike phase. The magnetic properties show ferro- and antiferromagnetic exchange interactions in the Cr2MII and Fe2MII series, respectively.

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