Short Communication
The electronic spectra of liquid ruthenium and molybdenum pentafluorides

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Abstract

The absorption spectra of liquid RuF5 and MoF5 have been recorded between 4000 cm-1 and 26 000 cm-1. Possible assignments are discussed.

References (9)

  • J.H. Canterford et al.

    Rev. Pure Appl. Chem.

    (1967)
  • A.J. Edwards et al.

    J. Chem. Soc.

    (1962)
  • J.H. Holloway et al.

    J. Chem. Soc.

    (1963)
  • T.M. Dunn

    Trans. Faraday Soc.

    (1961)
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Cited by (8)

  • MoF<inf>5</inf> revisited. A comprehensive study of MoF<inf>5</inf>

    2018, Journal of Fluorine Chemistry
    Citation Excerpt :

    Interestingly, though, mass spectroscopic and electron-diffraction studies on overheated vapors of MoF5 report the molecule to be stable at temperatures as high as 280 °C [6,7]. Additional properties of MoF5 have been reported, albeit not a lot of work has been done on MoF5 since the 1970′s. UV–Vis [8], IR [9,10], and Raman data [9–11] are available for MoF5, however, little to no explanation of the bands arising from these spectra is given in these works. The magnetic and electronic properties [12–14], vapor pressure curve [4], and other thermodynamic properties [3] of MoF5 have also been studied.

  • The Halides of Molybdenum

    1994, Studies in Inorganic Chemistry
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Present address: John Hopkins University, Applied Physics Laboratory, 8621 Georgia Ave., Silver Spring, Md. 20910, U.S.A.

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