The measurement of Henry's constant for hydrogen in high subcritical and supercritical aqueous systems
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2020, Geochimica et Cosmochimica ActaThermodynamic properties of dilute hydrogen in supercritical water
2018, Fluid Phase EquilibriaCitation Excerpt :This particular case was thoroughly investigated by O'Connell and coworkers for correlating the infinite dilution partial molar volumes of many “gases” in various solvents [14], and of a number of electrolytes [15,22] and “gases” [19,21,22] in water over wide temperature and pressure ranges. There are a few other works [55–57] reporting the chemical potentials of dilute hydrogen in water at supercritical temperatures: at 973 K and 80 MPa [55], at 673 and 723 K and 27.5 MPa [56], at 658–723 K and 25 MPa [57]. However, these studies appear to be less precise (the scatter of reported Henry's constants may be up to 50% of the value [57]), they are performed at water densities below 300 kg m−3, and thus cannot provide a definite test of the quality of various models for predicting thermodynamic properties of H2 in its dilute aqueous solutions.
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