Application of transition metals in hydroformylation annual survey covering the year 2002

https://doi.org/10.1016/S0010-8545(03)00035-3Get rights and content

Abstract

Hydroformylation in homogeneous and heterogeneous systems, and hydroformylation related reactions of carbon monoxide reported in 2002 are reviewed.

Section snippets

Cobalt catalysts

The cobalt-catalyzed hydroformylation of 1,2-epoxyhex-5-ene (1) at 100 °C and 100 bar CO:H2=1:1 pressure was found to give the mixture of aldehyde isomers 2 and 3 in 99% yield [1].

It was found that the initial rate of Co2(CO)8-catalyzed cyclohexene hydroformylation and triethyl orthoformate carbonylation as well as the initial rate of CoH(CO)4 formation from Co2(CO)8 and H2 is reduced by the addition of dinitrogen, argon, or xenon. It is assumed that the additional gas competes with one or more

Silylformylation, silylcarbocyclization, and hydrogermylcarbonylation

Rhodium-catalyzed silylformylation has been applied in a highly efficient synthesis of polyketides by tandem intramolecular silylformylation–crotylsilylation [93].

The rhodium-catalyzed (0.5 mol.% Rh4(CO)12 and 10 mol.% P(OEt)3) carbonylative silylcarbocyclization reaction of 1,6-enynes such as 35 at 105 °C and 20 bar of CO in 1,4-dioxane was found to afford 36 as essentially the sole product in 91% isolated yield [94].

The palladium–phosphite complex from [PdCl(η3-C3H5)]2 and (2,5-di-tBuC6H3O)3P (

Reviews

  • 1

    Recent advances in rhodium-catalyzed cyclization reactions. A review with 44 references of cyclohydrocarbonylation processes (a combination of hydroformylation and cyclization), which serve for the rapid construction of monocyclic, bicyclic, and fused ring systems from readily obtainable starting materials [126].

  • 2

    New cyclization reactions in organic syntheses. A review with 18 references of the transition metal-catalyzed cyclization reactions developed in the author's laboratories, which include

Acknowledgements

The author thanks the Hungarian Science Fund for support under Grant No. OTKA T037817.

References (137)

  • C. Botteghi et al.

    J. Mol. Catal. A: Chem.

    (2002)
  • D. He et al.

    Catal. Commun.

    (2002)
  • C.R. Yonker et al.

    J. Organomet. Chem.

    (2002)
  • M. Seepersaud et al.

    Tetrahedron Lett.

    (2002)
  • M. Seepersaud et al.

    Tetrahedron Lett.

    (2002)
  • A.R. Sanger

    J. Mol. Catal. A: Chem.

    (2002)
  • P. Suomalainen et al.

    J. Mol. Catal. A: Chem.

    (2002)
  • G. Frison et al.

    C. R. Chim.

    (2002)
  • A.C. da Silva et al.

    J. Mol. Catal. A: Chem.

    (2002)
  • E. Engeldinger et al.

    C. R. Chim.

    (2002)
  • P. Kandanarachchi et al.

    J. Mol. Catal. A: Chem.

    (2002)
  • G. Keglevich et al.

    J. Organomet. Chem.

    (2002)
  • X. Liu et al.

    J. Organomet. Chem.

    (2002)
  • Y. Wang et al.

    J. Mol. Catal. A: Chem.

    (2002)
  • M. Diéguez et al.

    Tetrahedron: Asymmetry

    (2001)
  • G. Franciò et al.

    Inorg. Chim. Acta

    (2002)
  • C. Saluzzo et al.

    J. Organomet. Chem.

    (2002)
  • M. Karlsson et al.

    Catal. Commun.

    (2002)
  • A. Aghmiz et al.

    J. Mol. Catal. A: Chem.

    (2002)
  • C. Erkey et al.

    Catal. Commun.

    (2002)
  • C.M. Foca et al.

    J. Mol. Catal. A: Chem.

    (2002)
  • A. Köckritz et al.

    J. Mol. Catal. A: Chem.

    (2002)
  • S. Rojas et al.

    J. Mol. Catal. A: Chem.

    (2002)
  • Y. Yuan et al.

    Catal. Today

    (2002)
  • E. Lindner et al.

    J. Organomet. Chem.

    (2002)
  • D.F. Foster et al.

    Tetrahedron

    (2002)
  • T. Mathivet et al.

    Tetrahedron

    (2002)
  • T. Mathivet et al.

    C. R. Chim.

    (2002)
  • Y. Huang et al.

    Catal. Commun.

    (2002)
  • C. Yang et al.

    Catal. Today

    (2002)
  • Y. Zhang et al.

    Catal. Today

    (2002)
  • M. Haumann et al.

    Appl. Catal. A: General

    (2002)
  • M. Haumann et al.

    Appl. Catal. A: General

    (2002)
  • H. Chen et al.

    Catal. Today

    (2002)
  • Y. Huang et al.

    J. Mol. Catal. A: Chem.

    (2002)
  • C. Yang et al.

    J. Mol. Catal. A: Chem.

    (2002)
  • Y. Wang et al.

    Catal. Today

    (2002)
  • P.C. Ford et al.

    Coord. Chem. Rev.

    (2002)
  • S. Haji et al.

    Tetrahedron

    (2002)
  • G. Lenoble et al.

    J. Organomet. Chem.

    (2002)
  • S. Jayasree et al.

    J. Mol. Catal. A: Chem.

    (2002)
  • M. Bianchi et al.

    Eur. J. Inorg. Chem.

    (2002)
  • R. Lazzaroni et al.

    Organometallics

    (2002)
  • L. Ren et al.

    J. Org. Chem.

    (2002)
  • H. Schumann et al.

    Eur. J. Inorg. Chem.

    (2002)
  • M.F. Sellin et al.

    J. Chem. Soc. Dalton Trans.

    (2002)
  • Y. Hu et al.

    Chem. Commun.

    (2002)
  • S.I. Fujita et al.

    New J. Chem.

    (2002)
  • E. Teoh et al.

    Chem. Commun.

    (2002)
  • C.R. Landis et al.

    J. Chem. Soc. Dalton Trans.

    (2002)

    • Cited by (0)

    View full text
    Copyright © 2003 Elsevier Science B.V. All rights reserved.