Research paperRole of amorphous ferric oxyhydroxide in removal of anthropogenic vanadium from seawater
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2022, Geochimica et Cosmochimica ActaCitation Excerpt :The scavenging of V by iron oxides has also been found in hydrothermal systems (Trefry and Metz, 1989; German et al., 1991). Experiments and models show that 100 % V can be adsorbed to ferrihydrite and goethite at pH ∼ 4 (Shieh and Duedall, 1988; Blackmore et al., 1996; Peacock and Sherman, 2004; Larsson et al., 2017b). The partition coefficient (Kds) of V between soil and water reaches 750,000 L kg−1 as calculated from experimental data, suggesting strong adsorption of V by soils (Huang et al., 2015).
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2019, Applied GeochemistryCitation Excerpt :The model was applied in a fully predictive mode to the two previously mentioned data sets of Shieh and Duedall (1988) and Blackmore et al. (1996). While the model overpredicted vanadate(V) adsorption for the data of Shieh and Duedall (1988) it underpredicted the binding slightly for the data set of Blackmore et al. (1996). This can probably be explained by different procedures for ferrihydrite synthesis and ageing, as well as different reaction times in the experiment.