Effect of rapid quenching on electrical properties of lithium conductive glasses
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2022, Sustainable Materials and TechnologiesCitation Excerpt :The most notable application of the quenching method is the fabrication of glass phases [22]. Common method is to melt the reagents such as Li2S and P2S5 inside the quartz tube at a temperature between 900 and 1100 °C followed by rapid reduction of the temperature by quenching in water or liquid nitrogen with a twin roller equipment [23,24]. This process is easy to reproduce, but it is rather energy-consuming [25,26] and is considered to be not feasible in large-scale production due to the requirement of sealing and quenching steps [27].
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2021, Journal of Non-Crystalline SolidsCitation Excerpt :Experimental investigations revealed that the electrical properties of lithium conductive glasses are greatly affected by the cooling rate. Pradel et al. studied rapid quenching effect on lithium-containing sulfide glasses and found that the room temperature conductivity of rapidly quenched samples could be almost an order of magnitude higher than that of the regular, air quenched glasses [18]. Yoshiyagawa and Tomozawa reported that rapid quenching of lithium and sodium silicate glass causes increase of DC conductivity [19].