Vanadium effect on the activity of horseradish peroxidase, catalase, glutathione peroxidase, and superoxide dismutase in vitro
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2010, Environmental Toxicology and PharmacologyCitation Excerpt :O2− and hydroperoxy radicals (HO2) have been shown to react directly with the membrane unsaturated fatty acids to result in LPO (Schaich, 1992). The studies of Serra et al. (1992) have demonstrated lack of a direct effect of vanadate and vanadyl on the activity of the main antioxidant enzymes (SOD and CAT), suggesting that many biological and toxicological effects of V may be mediated by oxidative reactions of the metal or of its complexes formed with physiologically relevant biomolecules, rather than by direct modulation of enzymatic activities. Therefore, a direct effect of SMV on SOD and CAT activity should be excluded.
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