A microthermogravimetric system for the measurement of vapour pressure by a transpiration method
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2021, Process Safety and Environmental ProtectionCitation Excerpt :Cyanides and nitrates were removed from the system of the equilibrium calculation. As thermodynamic data of gaseous CdCl and CdCl2 were not included in the commercial database, we estimated them using statistical thermodynamics (Knox, 1971) with molecular parameters (Shepler and Peterson, 2006) and vapor pressure data (Bloom and Welch, 1958; Keneshka and Cubiociotti, 1964; Dharwadkar et al., 1993). Gaseous CdOH and Cd(OH)2 were removed from the equilibrium calculation because solid cadmium hydroxide decomposes to solid CdO at least above 410 °C (Low and Kamel, 1965; Fahim and Kolta, 1970; Schofield, 2020), and we could not find references detecting gaseous cadmium hydroxides over heated cadmium hydroxide.
Thermodynamic stability of Li<inf>3</inf>ThF<inf>7</inf>(cr) and LiTh<inf>4</inf>F<inf>17</inf>(cr)
2021, Journal of Alloys and CompoundsCitation Excerpt :A dynamic vertical transpiration system consisting of a micro thermo balance (SETARAM, Model B-24) having mass sensitivity of ±0.1 μg was used for vapour pressure measurements in the present study. The sketch diagram of transpiration apparatus used in the present experiment, details of the equipment and experimental method have been described elsewhere [21–23]. It was calibrated for the measurement of vapour pressure by using CdI2 as standard [23].
Thermodynamic stability of SrThF<inf>6</inf>(cr) and BaThF<inf>6</inf>(cr)
2018, Journal of Alloys and CompoundsCitation Excerpt :Fig. 1 gives the sketch diagram of transpiration apparatus used in the present experiment. Details of this transpiration equipment have been described elsewhere [13]. The novel dynamic vertical transpiration system consisting of a micro thermo balance (SETARAM, Model B-24) had mass sensitivity of ±0.1 μg.
Polonium evaporation from dilute liquid metal solutions
2014, Journal of Nuclear MaterialsCitation Excerpt :The transpiration method, used for the investigation of Po vapor pressure over liquid metals in this study (in literature also described as transportation method), is a dynamical vapor pressure determination method. The saturation vapor pressures of many metals [14] and alloys [15] as well as organic [16] and inorganic [17] substances were determined using this technique. The fundamental principles of the method will be described in the following section.
Determination of thermodynamic stability of lanthanum chloride hydrates (LaCl<inf>3</inf>×xH<inf>2</inf>O) by dynamic transpiration method
2014, Journal of Alloys and CompoundsDesferrioxamine-cadmium as a 'Trojan horse' for the delivery of Cd to bacteria and fungi
2013, Journal of Trace Elements in Medicine and BiologyCitation Excerpt :The final decomposition of the cadmium complex occurs at higher temperature (ca. 700 °C) than the dfo ligand (ca. 640 °C). No residues for the two metal-containing samples were found above 700 °C, since cadmium halides are volatile [31] and possibly any other chlorine and cadmium-containing organic intermediate formed are also volatile in the temperature range of 500–700 °C. Mass spectrometry data of the volatile species generated in the thermal decomposition of the different compounds (Fig. 2) indicate mainly the processes of the organic matter oxidation up to temperatures of about 400 °C (release of fragments with m/z = 44, CO2, and m/z = 18, H2O) and the oxidation of elementary carbon (release of CO2 primarily) at higher temperatures (ca. 550–700 °C).