A new synthesis of alkylated 2H-pyran-2-ones and its application to the determination of the relative and absolute configuration of supellapyrone, sex pheromone of the brownbanded cockroach, Supella longipalpa
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Supellapyrone (1) can be synthesized by direct coupling of a bromopyrone (i) with an alkylzinc reagent (ii). The absolute configuration of the pheromone has been assigned as .
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Copyright © 1994 Published by Elsevier Ltd.