Li3N: A promising Li ionic conductor
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2022, Energy Storage MaterialsCitation Excerpt :The EDS spectrum in Fig. S11 clarifies the homogenous distribution of N element on the top of LAG, and the corresponding N 1s XPS spectrum in Fig. S12 also supports the presence of Li3N (399.6 eV) on the LAG surface. Li3N is a promising SEI component with a high ionic conductivity of 10‒3 S cm−1 to facilitate the fast migration of Li+ through SEI and stabilize the electrode/electrolyte interface [45]. It can also account for the reduced overpotential and prolonged cycling life of the LAG symmetric cell as shown in Fig. 3d−g.
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