Lipophile exchange membranes as electroactive assemblies on electrode surfaces

doi:10.1016/0022-0728(90)87244-E

Journal of Electroanalytical Chemistry and Interfacial Electrochemistry

Volume 296, Issue 1, 10 December 1990, Pages 221-231

https://doi.org/10.1016/0022-0728(90)87244-E Get rights and content

Abstract

Electroactive assemblies on glassy carbon electrodes have been prepared by incorporation of lipophilic quinones into lipophile exchange membranes composed of poly(Nmethyl-4-vinylpyridinium dihexadecylphosphate) (PVPMe⁺ DHP⁻). These assemblies exhibit stable electrochemical responses when immersed in aqueous solutions. The electrochemical response of quinone - PVPMe⁺ DHP⁻ layers prepared from short and long chain 2-alkylaminoanthraquinones depends on the nature of the quinone lipophile, mol% of quinone within the layer, PVPMe⁺ : DHP⁻ ratio, and pH of the contacting aqueous solution. Superior performance is observed in basic solutions with low mol% quinone.

References (47)

O. Haas et al.
J. Electroanal. Chem.
(1980)
C. Degrand et al.
J. Electroanal. Chem.
(1981)
L.L. Miller et al.
J. Electroanal. Chem.
(1984)
V.K. Gater et al.
J. Electroanal. Chem.
(1987)
V.K. Gater et al.
J. Electroanal. Chem.
(1988)
M.C. Pham et al.
J. Electroanal. Chem.
(1984)
M.C. Pham et al.
J. Electroanal. Chem.
(1986)
S. Cosnier et al.
J. Electroanal. Chem.
(1985)
A.F. Diaz et al.
J. Electroanal. Chem.
(1980)
P. Audebert et al.
J. Electroanal. Chem.
(1987)

K. Doblhofer et al.

J. Electroanal. Chem.

(1986)

X. Chen et al.

J. Electroanal. Chem.

(1987)

B. Lindholm et al.

J. Electroanal. Chem.

(1986)

H. Daifuku et al.

J. Electroanal. Chem.

(1985)

K.A.Bunding Lee et al.

J. Electroanal. Chem.

(1988)

B.L. Funt et al.

J. Electroanal. Chem.

(1983)

R.W. Murray

Annu. Rev. Mater. Sci.

(1984)

L.R. Faulkner

Chem. Eng. News

(1984)

J.P. Collman et al.

J. Am. Chem. Soc.

(1980)

R.F. Lane et al.

J. Phys. Chem.

(1973)

M.D. Liu et al.

J. Chem. Soc., Chem. Commun.

(1990)

P.R. Moses et al.

Anal. Chem.

(1975)

Cited by (0)

^★: Present address: Department of Chemistry, Indiana State University, Terre Haute, IN 47809, U.S.A.

View full text