ArticleChiral metal complexes 41. Stereoisomerism in palladium(II) complexes of a series of chiral bis-picolyl N4-tetradentate ligands☆
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Molybdenum complexes of chiral C<inf>2</inf>-symmetric picchxn-type ligands: Synthesis, characterization, and structural studies
2015, Inorganica Chimica ActaCitation Excerpt :Picchxn-type ligands (N4 ligands, trans-N,N′-bis(heterocycl-2-ylmethyl)-1,2-diaminocyclohexanes) have been studied extensively on small 3d metals, with applications having been reported for Mn(II) [9–21], Fe(II) [19,22–32], Fe(III) [27], Fe(IV) [33–35], Co(III) [7,8,36–40], Cu(I) [41,42], Cu(II) [41,43], and Zn(II) [44,45] centers. The literature also includes reports of picchxn-type ligands on Cr(III) [8,46,47] as well as sparse Ru(II) [7,24,48–50], Rh(III) [51], Pd(II) [52], Ag(I) [43,53], and Cd(II) [54,55] examples, but the behaviors of these ligands on larger low-valent metal centers remains largely uninvestigated. Our interest in picchxn-type ligands stems from ongoing studies of low-valent π-basic molybdenum complexes with potential applications in dearomatization sequences [56–59].
Coordination behaviour in transition metal complexes of asymmetric NPN ligands
2011, PolyhedronCitation Excerpt :In a related bidentate N3P system and a quinoline-phosphite the Pt–P bond lengths average 2.229(3) Å [10] and 2.156(3) Å [11], respectively. For further comparison the Pt–P bond averages 2.173(2) Å in cis-[PtCl2{P(OMe)3}2] [12] and 2.263(2) Å in cis-PtCl2(PEt3)2 [13]. A number of complexes of alkylaminophosphines have nitrogen atoms that are approximately planar [8a]; this is certainly not the case here where the sum of the angles about the two nitrogens are 331° and 336°, respectively which is further towards a tetrahedral arrangement than in other diaminoalkylphosphine complexes where more planar nitrogens are observed [ΣN = 344° and 340°] [1b].
A spectroscopic investigation of the self-association and DNA binding properties of a series of ternary ruthenium(II) complexes
2005, Journal of Inorganic BiochemistryDesign of chiral picen-based metal complexes for molecular recognition of α-aminoacids and nucleic acids
1997, Coordination Chemistry Reviews
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Part 40 is M.A. Cox, P.D. Newman, F.S. Stephens, R.S. Vagg and P.A. Williams, Inorg. Chim. Acta, 221 (1994) 191.