Elsevier

Chemical Physics Letters

Volume 103, Issue 6, 20 January 1984, Pages 443-446
Chemical Physics Letters

Search for the kramers theory turnover: photochemical isomerization at very low viscosities

https://doi.org/10.1016/0009-2614(84)85273-2Get rights and content

Abstract

The rate of photochemical isomerization of diphenyl butadiene has been studied as a function of viscosity and temperature in liquid ethane and propane. The lowest viscosity studied is about one order of magnitude lower than our previous study. No evidence for a turnover or decrease in rate with decreasing viscosity was found.

References (19)

  • H.A. Kramers

    Physica

    (1940)
  • S.P. Velsko et al.

    J. Chem. Phys.

    (1982)
  • C.V. Shank et al.

    J. Chem. Phys.

    (1978)
  • D.L. Hasha et al.

    J. Chem. Phys.

    (1981)
    D.L. Hasha et al.

    J. Am. Chem. Soc.

    (1982)
  • J.A. Montgomery et al.

    J. Chem. Phys.

    (1980)
  • R.F. Grote et al.

    J. Chem. Phys.

    (1982)
  • B. Carmeli et al.

    Phys. Rev. Letters

    (1982)
  • a B. Carmeli, A. Nitzan., J. Chem. Phys. to be...B. Carmeli et al.

    Phys. Rev. Letters

    (1983)
  • D.K. Garrity et al.

    Chem. Phys. Letters

    (1983)
There are more references available in the full text version of this article.

Cited by (61)

  • Cis-Trans isomerization of C=C double bonds

    2003, Photochromism: Molecules and Systems
View all citing articles on Scopus
1

Camille and Henry Dreyfus Teacher-Scholar.

View full text