Elsevier

Lithos

Volumes 198–199, June 2014, Pages 117-128
Lithos

Moho transition zone in the Cretaceous Andaman ophiolite, India: A passage from the mantle to the crust

https://doi.org/10.1016/j.lithos.2014.03.027Get rights and content

Highlights

  • Moho transition zone documents melt–mantle interaction and fractional crystallization.

  • Olivine-rich troctolites record impregnation of MORB melt into replacive dunite.

  • The composition of the impregnated melt is indistinguishable with the gabbroic rocks.

  • Clinopyroxenites formed from a melt genetically linked with the replacive dunite.

Abstract

We examined the composition and lithological variability from a road section in south-Andaman which represents a pathway to the crustal section of the Cretaceous Andaman ophiolite. Like other well-studied ophiolites worldwide this transition zone is marked by association of olivine-rich troctolite, wehrlite, pyroxenite and gabbroic rocks. The mineral chemical variations document the evolution of this zone by melt–mantle interaction and fractional crystallization. Petrographic evidence suggests that water was introduced during the evolution of this transition zone. The olivine-rich troctolites record impregnation of MORB melt into a residual olivine-rich lithology (replacive dunite) that formed by an earlier episode of melt–peridotite interaction at a slow spreading ridge. The clinopyroxenites indicate formation from an extreme clinopyroxene saturated melt that might be genetically linked with the formation of olivine-rich protolith of the troctolitic rocks prior to melt impregnation. The wehrlite crystallized from the melt residual after the formation of clinopyroxenite. The composition of the impregnating melt that transformed the replacive dunite to olivine-rich troctolite is identical to the gabbroic rocks. We conclude that the association of these rock types from south-Andaman provides us with a snapshot of the switch over of geodynamic setting of the Andaman ophiolite (MOR to arc) as preserved presently between north-Andaman in the north and Rutland Island in the south.

Introduction

The Moho transition zone (MTZ) in an ophiolite sequence represents a zone of magmatic exchange between mantle and the oceanic crust. Compositionally this zone demarcates a gradational zone from the uppermost residual mantle peridotites from which melt is extracted to the base of continuous gabbroic rocks, an unequivocal crystallization product from magma that initiates the formation of oceanic crust. This gradational zone signifies the location where crystallization takes place prior to formation of the oceanic crust. However, crystallization may start in melt channels deeper in the mantle as observed in abyssal peridotites (e.g. Dantas et al., 2007, Dick and Natland, 1996, Seyler et al., 2001), in ophiolites (e.g., Ceuleneer et al., 1996, Python and Ceuleneer, 2003, Varfalvy et al., 1997) and as inferred from MORB composition (e.g., Grove et al., 1992).

The MTZ may vary in thickness from few meters to several hundreds of meters. Thick MTZ characterized by vertical mantle flow occurs above Maqsad diapir of Oman, whereas thin MTZ correlates with off-axis mantle flow away from the diapir (Rabinowicz et al., 1987). Nevertheless, this cannot be systematically generalized because there are places where thick dunitic horizons are observed with no evidence of vertical mantle flow. This is the case, among others, of the Wadi Thuqbah area of Oman (Negishi et al., 2013), of the Trinity ophiolite (Ceuleneer and le Sueur, 2008), and of Newfoundland ophiolites (Suhr et al., 2003). Lithologically the MTZ is dominated by olivine-rich rocks (mainly dunitic) which are commonly impregnated, and host discontinuous bands or lenses of wehrlites, troctolites and gabbros. The MTZ was initially thought to be the bottommost part of the crustal section mainly because of the notion that the lithological variations observed in this zone may be explained by mineral fractionation from a mid-ocean ridge basaltic magma. Accordingly, a cumulus origin of the MTZ was proposed (Elthon, 1979, O'Hara, 1965). Subsequent work, however, on samples collected during the Ocean Drilling Program (and submersible dive operations) (Dick et al., 2010, Sanfilippo et al., 2013, Suhr et al., 2008) and studies carried out on several ophiolite sections (Benoit et al., 1996, Ceuleneer, 1991, Clenet et al., 2010, Jousselin and Nicolas, 2000, Koepke et al., 2009, Koga et al., 2001, Python and Ceuleneer, 2003, Renna and Tribuzio, 2011, Sanfilippo and Tribuzio, 2013) propose a primarily residual mantle origin for the host dunites (replacive), formed largely by melt–mantle reaction. Significantly, however, the origin of this dunitic transition zone (DTZ) is still debated and recently, Abily and Ceuleneer (2013) from their study on the Oman ophiolite argued that the dunitic rocks in the mantle–crust transition zone, although dominantly residual in origin in their lowermost parts, grade into cumulate dunite at the top.

This paper will focus on the nature and origin of the MTZ in the Andaman ophiolite, India, based on detailed field, petrographic, mineral chemical and petrological studies. Although the lithological diversity of the mantle peridotites from this ophiolite has been described in many recent papers (e.g., needs references here) the identification of MTZ and its characterization with reference to melt percolation through this zone have not yet been attempted. The main objective of this paper is to determine the sequential formation of various rock types, explaining their association from a mantle-borne basaltic melt continuously evolving through this zone. Characterisation of various MTZ rock types in this section of oceanic lithosphere gives us an insight to the processes of melt extraction (likely episodic) from the shallow mantle below the paleo-Indian Ocean and migration of the evolving melt through the transition zone to form the crustal sequence. This study records a progressive geodynamic evolution of the Cretaceous Andaman ophiolite which had its origin at mid-ocean ridge and was later modified by subduction.

Section snippets

Andaman ophiolite — an overview

The Andaman Islands, lying east of the Java trench expose dismembered bodies of Cretaceous (~ 95 Ma, Pedersen et al., 2010) ophiolite slices at their eastern margin between Rutland Island in the south and north-Andaman in the north as a result of subduction of the Indian plate obliquely beneath the Burma sub-plate, a part of the much larger Eurasian plate (Luhr and Haldar, 2006) (Fig. 1). The islands consist of four major stratigraphic units viz. Cretaceous Ophiolite Group, Eocene Mithakhari

Petrography

The lower contact of the olivine-rich troctolites with the mantle peridotites is not exposed in this section. The olivine rich rocks are extremely altered (olivine up to 30 vol.%). The contact with the overlying clinopyroxenite is sharp without any indentation or reaction features. Petrographically, these troctolites are orthopyroxene-free and everywhere show features of melt impregnation (Fig. 3). The shape of olivine grains ranges from subhedral to rounded, while plagioclase and clinopyroxene

Analytical methods

Major element analyses of olivines, pyroxenes, plagioclases and chromian spinels were determined at Kanazawa University with an Electron Probe Micro Analyser (EPMA) (JEOL JXA-8800 Superprobe) at an accelerating voltage of 20 kV, a beam current of 20 nA and using a beam diameter of 3 μm. Both natural and synthetic minerals were used as standards. Raw data were corrected using ZAF online correction program. The Fe2 +–Fe3 + partitioning in chromian spinel was calculated assuming spinel stoichiometry.

Major element mineral chemistry

Olivine shows an appreciable range in compositions in all the rock types (Supplementary data). In olivine-rich troctolites they are distinctive with Fo mol% ~ 90, similar to that of mantle peridotites (Ghosh et al., 2013). NiO content of this rock is higher (up to 0.35 wt.%) relative to other rock types (Fig. 4a). Fo content in gabbroic rocks is much lower, ranging between 78 and 85, which is very akin to Oman gabbros. Olivines in wehrlitic rocks have comparable MgO content with that in

Trace element chemistry

Since clinopyroxene is the main reservoir for many incompatible trace elements in ultramafic and gabbroic rocks it is a good proxy for bulk composition. Further, owing to its common presence in all the lithotypes of present study, we analyzed representative clinopyroxenes from all the rock types (Supplementary data). The chondrite-normalized REE patterns for clinopyroxenes show broadly similar patterns with varying concentrations for different rock types (Fig. 10). The HREE pattern is

Discussion

With the given lithological variations and geochemical diversity reported in this study, a single fractionation history involving a common magma appears unrealistic and therefore multiple intrusions of batches of melt are required to explain this diversity. Clinopyroxene is the only mineral present in all the rock types and is the predominant fractionating mineral at least at the initial stage of crystallization history. Thus, additional process is required to explain this extreme clinopyroxene

Acknowledgments

Several phases of field work for this research was supported with funds partly from the Indian National Science Academy (INSA)Japan Society for the Promotion of Science (JSPS) Bilateral Exchange Program for joint collaborative research given to TM and the rest from the Department of Science and Technology, India (SR/FTP/ES-65/2009) given to BG. BG also acknowledges the support of JSPS Invitation Fellowship for final completion of this work. H. Whitechurch and one anonymous reviewer are deeply

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      A cumulus origin of the MTZ was proposed initially, however, later works are more inclined to melt-mantle interaction. A plethora of studies on various ophiolite suites across the globe (Abily and Ceuleneer, 2013; Clénet et al., 2010; Ghosh et al., 2014; Jousselin and Nicolas, 2000; Kelemen et al., 1995; Koga et al., 2001; Mazzucchelli et al., 2009; Quick, 1981; Renna and Tribuzio, 2011; Suhr et al., 2003; Uysal et al., 2012) and drilled cores collected during Ocean Drilling Program (Arai and Takemoto, 2007; Dick et al., 2006; Dick et al., 2010; Dick and Natland, 1996; Ildefonse et al., 2006; Sanfilippo et al., 2013; Suhr et al., 2008) recognized that the MTZ from its base to middle section is predominantly composed of replacive dunite. The replacive dunite originates through melt-mantle interaction (Abily and Ceuleneer, 2013; Akizawa and Arai, 2009; Ceuleneer et al., 1996; Dick and Natland, 1996; Kelemen et al., 1995; Koga et al., 2001; Nicolas and Prinzhofer, 1983; Piccardo et al., 2007), grading up-section to cumulus dunite formed by fractional crystallization of olivine from mid-ocean ridge basalt (MORB) parent melts (Abily and Ceuleneer, 2013; Quick, 1981).

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