Skip to main content
Log in

Double slag operation dephosphorization in BOF for producing low phosphorus steel

  • Published:
Journal of Iron and Steel Research International Aims and scope Submit manuscript

Abstract

A study on the production of low phosphorus steel by double slag operation in 210 t converter was carried out. A phosphorus content of less than 0.005% (mass percent) was obtained before tapping. About 80% phosphorus could be removed by the first slag after 5 min. High Fe3+ content and high basicity in the first slag were in favor of dephosphorization. On the other hand, Fe3+ content had less effect on dephosphorization during second slag treatment. In the second slag period, the fraction of dephosphorization increased with the increase of basicity up to a basicity of 6. Further increase of basicity of the second slag had very little effect on dephosphorization. The tapping temperature had great impact on dephosphorization. It was impossible to get phosphorus less that 0.005% when the tapping temperature was higher than 1 943 K. The optimum operation conditions were suggested. On the basis of these conditions, the amount of the second slag and the effect of the remaining first slag were estimated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Hernandez A, Morales R D, Romero A, et al. Dephosphorization Pretreatment of Liquid Iron [A]. 55th Ironmaking Conference Proceeding [C], Pittsburgh: Iron and Steel Society, 1996. 27.

    Google Scholar 

  2. Ohnishi T. Pretreatment Technique of Hot Metal by Newly Developed Refining Furnace [J]. Kobe Steel Engineering Reports, 1988, 38(1): 9.

    Google Scholar 

  3. Ina M. Metallurgical Characteristics of LD Type Hot Metal Pretreatment [J]. CAMP-ISIJ, 1991, 4(4): 1154.

    Google Scholar 

  4. Yoshida K. Development of Effective Refining Process Consisting of Both Hot Metal Pretreatment and Decarbrization in Two Top and Bottom Blown Converters [J]. Testu-to-Hagane, 1990, 76(11): 1817.

    Article  Google Scholar 

  5. Wakamatsu S. Dephosphorization at Hot Metal Pretreatment in a BOF Vessel [J]. CAMP-ISIJ, 1996, 9(9): 864.

    Google Scholar 

  6. Barradell D V. The Development of Secondary Steelmaking Process Routes for the Successful Continous Casting of Flat Product [A]. 2nd European Contiuous Casting Conf/6th International Rolling Conf [C]. Dusseldorf: VDEh, 1994. 1.

    Google Scholar 

  7. TIAN Zhi-hong, AI Li-qun, CAI Kai-ke, et al. Deep Dephosphorization of Liquid Steel With CaO-CaF2-FeO Slags [J]. Journal of Iron and Steel Research, 2004, 16(5): 23 (in Chinese).

    Google Scholar 

  8. TIAN Zhi-hong, CAI Kai-ke, WANG Xin-hua, et al. Deep Dephosphorization Ability of BaO-CaO-CaF2 Flux for Liquid Steel [J]. Journal of University of Science and Technology Beijing, 2005, 27(3): 294 (in Chinese).

    Google Scholar 

  9. Hayashi K, Ikeda M, Katagiri H. Dephosphorization of Liquid Steel by Sodium Carbonate [J]. Transactions ISIJ, 1984, 24: B-207.

    Article  Google Scholar 

  10. TIAN Zhi-hong, CAI Kai-ke, WANG Xin-hua, et al. Thermodynamic Study on BaO-CaO-CaF2 Slags Used for Dephosphorization of Molten Steel [J]. Journal of Iron and Steel Research, 2005, 12(3): 5.

    Google Scholar 

  11. Csrlo Borgianni, Renato D’Angelo. Deep Dephosphorization Treatments for Steel [J]. Ctajib, 1991, (3): 27.

    Google Scholar 

  12. TIAN Zhi-hong, JIANG Jun-pu, CAI Kai-ke, et al. Effects of Oxygen Potential and Flux Composition on Dephosphorization and Rephosphorization of Molten Steel [J]. Journal of University of Science and Technology Beijing, 2005, 12(5): 494.

    Google Scholar 

  13. Care Wagner. Concept of Basicity of Slags [J]. Metall Trans, 1975, 6B: 405.

    Google Scholar 

  14. Nakamura S, Tsukihashi F, Sano N. Phosphorus Partition Between CaOsatd-BaO-SiO2-Fe2O Slags and Liquid Iron at 1 873 K [J]. ISIJ International, 1993, 33(1): 53.

    Article  Google Scholar 

  15. Liang Y J. The Physical Chemistry [M]. Beijing: Metallurgy Industry Press, 1995.

    Google Scholar 

  16. Sigwork G K, Elliott J F. The Thermodynamics of Liquid Dilute Iron Alloys [J]. Metal Science, 1974, 18: 298.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zhi-hong Tian.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tian, Zh., Li, Bh., Zhang, Xm. et al. Double slag operation dephosphorization in BOF for producing low phosphorus steel. J. Iron Steel Res. Int. 16, 6–14 (2009). https://doi.org/10.1016/S1006-706X(09)60036-4

Download citation

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1016/S1006-706X(09)60036-4

Key words

Navigation