Structures of transition metal hydrides determined by neutron diffraction

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Abstract

Neutron diffraction structure determinations of transition metal hydrides have been reviewed. Molecular complexes as well as solid state compounds are surveyed; both structures determined by single-crystal and powder neutron diffraction are included. Tables of average MH distances have been compiled.

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      It is perhaps because of these applications that metal hydrides continue to garner interest [1f]. Hydrogen atoms have generally been difficult to locate using X-ray diffraction because of their low electron density, so neutron diffraction has been the method of choice when studying metal-hydrogen interactions [2]. But unfortunately, neutron diffraction generally requires large crystals (on the order of 1 mm3 in volume) which was difficult to obtain in our study.

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