Size selective photoluminescence excitation spectroscopy in CdSe nanocrystals

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Abstract

We present a photoluminescence excitation study of CdSe nanocrystals embedded in a silicate glass matrix. The band edge emission was found to be strongly dependent on the excitation photon energy (hvL) when hvL is much higher than the fundamental absorption peak. Using the theoretical energies of electronic states in CdSe nanocrystal calculated by Ekimov et al. [J. Opt. Soc. Am. B 10, 100 (1993)] we showed our results can be understood as a size-selective effect. We also show that it is possible to use such excitation spectroscopy to determine the excited state energies and also the size distribution in nanocrystal samples.

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