Ring metalation of toluene by butyllithium in the presence of N,N,N′,N′-tetramethylethylenediamine

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Cited by (48)

  • NMR spectroscopic study of the adduct formation and reactivity of homoleptic rare earth amides with alkali metal benzyl compounds, and the crystal structures of [Li(TMEDA)<inf>2</inf>][Nd{N(SiMe<inf>3</inf>)<inf>2</inf>}<inf>3</inf>(CH<inf>2</inf>Ph)] and [{Li(TMP)}<inf>2</inf>{Li(Ph)}]<inf>2</inf>

    2018, Journal of Organometallic Chemistry
    Citation Excerpt :

    TMP(H) was dried over activated 4 Å molecular sieves, TMEDA was dried over CaH2 and distilled, and LiN″ was sublimed prior to use. The following compounds were prepared according to literature methods: [Li(Ph)] [68], [Li(TMP)] [39], [Li(TMEDA)(CH2Ph)] [69], [Na(CH2Ph)] [60], [K(CH2Ph)] [70], [Y(N″)3] [71], [Ce(N″)3] [9,72], [Nd(N″)3] [73], and [Ce(TMP)3] [55,56]. NMR spectra were recorded on Bruker AVI400 or AVIII400 spectrometers and the chemical shifts δ are noted in parts per million (ppm) calibrated to the residual proton resonances of the deuterated solvent.

  • Synthesis of organometallic polymers. Review

    1984, Polymer Science U.S.S.R.
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Part of a paper presented at the 3rd Intern. Symp. on Organometallic Chemistry, Munich, Germany, August, 1967.

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