Crystal structure and solution dynamics of the lutetium(III) chelate of DOTA
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A comparison of the structural chemistry of scandium, yttrium, lanthanum and lutetium: A contribution to the group 3 debate
2022, Coordination Chemistry ReviewsCitation Excerpt :A similar situation exists in 3(Na[Sc(DOTA)]), NaOH·18H2O [110]. In contrast, Na[Lu(DOTA)(H2O)].4H2O and Na[Y(DOTA)(H2O)].4H2O both have nine-coordinate metal centres in the solid state [111,112] adopting a monocapped square antiprism with a coordinated water molecule occupying the capping site (Fig. 24. However, in the case of lutetium EXAFS measurements have failed to locate a coordinated water molecule in solution [113].
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