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Polymeric carbon nitrides produced from different gaseous conditions and their photocatalytic performance for degrading organic pollutants

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Abstract

Polymeric carbon nitride (p-C3N4) is a promising platform as a metal-free photo-catalyst for various reactions. The p-C3N4 can be produced by thermal poly-condensation of organic precursors. Their morphological and chemical structures depend on reaction conditions during the poly-condensation. In this study, two p-C3N4 materials are produced by heat treatment of urea under different gaseous conditions with air (urea-derived carbon nitride under air, UCN-A) and N2 (UCN-N), respectively. UCN-A and UCN-N samples are mesoporous materials and show excellent photocatalytic activities for degrading rhodamine B, an organic pollutant, under the irradiation of visible light. The UCN-A shows the better photocatalytic activity than UCN-N. Various characterizations reveal that more porous structures and larger surface areas of UCN-A are reasons for the better photocatalytic performance.

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Data availability

The datasets used in the current study are available from the corresponding author on reasonable request.

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Acknowledgements

This work was supported by Inha University Research Grant. We thank the Busan Center at the Korea Basic Science Institute (KBSI) for XPS analysis.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Inha University, 100 Inha-Ro, Michuhol-Gu, Incheon, 22212, Republic of Korea

    Dawoon Jang, Seokhyeon Jeon, Eun Young Shin & Sungjin Park

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  1. Dawoon Jang
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Correspondence to Sungjin Park.

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Jang, D., Jeon, S., Shin, E.Y. et al. Polymeric carbon nitrides produced from different gaseous conditions and their photocatalytic performance for degrading organic pollutants. Carbon Lett. 33, 803–809 (2023). https://doi.org/10.1007/s42823-023-00461-y

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  • DOI: https://doi.org/10.1007/s42823-023-00461-y

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