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Characterization and Thermal Degradation Study of Carbonization the Polyimide (PMDA/ODA)/Fe Composite Films

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Abstract

The carbonization performance of the iron-containing carbon film resulting from polyimide was examined, Polyimide/Fe composite films were prepared from Iron (III) 2,4-pentanedionate (Fe(acac)) and poly(amic acid) (PAA) based on ODA and PMDA via a solution process in DMAC, followed by carbonization the polyimide film at a temperature range of 600–1600 °C. The organized polyimide/Fe combined films were characterized using a scanning electron microscope (SEM), and thermogravimetric analysis (TGA), X-ray diffraction (XRD), and Raman. The formation of Fe particles and the synthesis of polyimide (PMDA/ODA) in the polyimide matrix is confirmed by FTIR results. Meantime, in the polyimide matrix, Fe particles were well spread which were showed by the SEM images. Kinetic parameters and thermal stability of the degradation methods for the organized polyimide/Fe combined films were examined in N2 environment by TGA. The results have shown that the values of the calculated activation energies and thermal stability increased of the (Fe (acac)) the activation energy and loading also different with the weight-loss rate for all compositions.

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Authors and Affiliations

  1. College Umm Al- Rabie of Technical Science, Benghazi, Libya

    Fathi Etaher Elbakoush

  2. Key Laboratory of Optoelectronic Devices and Systems, Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen, 518060, China

    Qudrat Ullah Khan

  3. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology China, Beijing, China

    Fathi Etaher Elbakoush, Mati Ullah, Afaq Ullah Khan & Javed Khan

  4. College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, 730070, Gansu, People’s Republic of China

    Arif Ullah

  5. Department of Pharmacy, Faculty of Pharmaceuticals Sciences, University of Faisalabad, Punjab, Pakistan

    Asra Iftikhar

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  1. Fathi Etaher Elbakoush
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Elbakoush, F.E., Khan, Q.U., Ullah, M. et al. Characterization and Thermal Degradation Study of Carbonization the Polyimide (PMDA/ODA)/Fe Composite Films. Trans. Electr. Electron. Mater. 22, 843–850 (2021). https://doi.org/10.1007/s42341-021-00309-0

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  • DOI: https://doi.org/10.1007/s42341-021-00309-0

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