Abstract
Free water available in calcium aluminate cement (CAC)-bonded castables is crucial for the hydration of CAC and the conversion of hydration products in the curing and drying processes, as both the hydration and conversion reactions are dissolution–precipitation reactions. To elucidate the effect of different levels of free water loss upon the hydration of CAC, the conversion of hydration products and the mechanical strength of the CAC-bonded castables, the CAC-bonded castables were subjected to sealed and unsealed curing conditions at 50 °C and drying at 110 °C. The results demonstrate that the fast removal of free water during unsealed curing would hinder the conversion from 2CaO·Al2O3·8H2O to 3CaO·Al2O3·6H2O and consequently prevent the deterioration of strength. As a comparison, although sealed-cured samples have less water loss and high degree of hydration of CAC, they still show lower strength than the unsealed samples after curing. The following drying process further accelerates the hydration of residual calcium aluminate clinkers for both the sealed and unsealed samples, but still does not favor the conversion from 2CaO·Al2O3·8H2O to 3CaO·Al2O3·6H2O in the unsealed-cured samples.
Similar content being viewed by others
References
C. Gogtas, H.F. Lopez, K. Sobolev, J. Eur. Ceram. Soc. 34 (2014) 1365–1373.
Y. Wang, X. Li, B. Zhu, P. Chen, Ceram. Int. 42 (2016) 11355–11362.
A.P. Luz, A.H.G. Gabriel, L.B. Consoni, C.G. Aneziris, V.C. Pandolfelli, Ceram. Int. 44 (2018) 2364–2375.
M. Roig-Flores, T. Lucio-Martin, M.C. Alonso, L. Guerreiro, Cem. Concr. Res. 141 (2021) 106323.
E. Sakai, T. Sugiyama, T. Saito, M. Daimon, Cem. Concr. Res. 40 (2010) 966–970.
M. Heikal, M.M. Radwan, O.K. Al-Duaij, Constr. Build. Mater. 78 (2015) 379–385.
W.E. Lee, W. Vieira, S. Zhang, K.G. Ahari, H. Sarpoolaky, C. Parr, Int. Mater. Rev. 46 (2001) 145–167.
C. Parr, L. Bin, B. Valdelièvre, C. Wöhrmayer, B. Touzo, The advantages of calcium aluminate cement containing castables for steel ladle applications, in: Proeedings of ALAFAR 2004, 2004, pp. 10–15.
A.P. Luz, V.C. Pandolfelli, Ceram. Int. 37 (2011) 3789–3793.
T.J. Chotard, M.P. Boncoeur-Martel, A. Smith, J.P. Dupuy, C. Gault, Cem. Concr. Comp. 25 (2003) 145–152.
B. Pacewska, M. Nowacka, J. Therm. Anal. Calorim. 117 (2014) 653–660.
H. Pöllmann, Rev. Miner. Geochem. 74 (2012) 1–82.
S.M. Bushnell-Watson, J.H. Sharp, Cem. Concr. Res. 16 (1986) 875–884.
B. Pacewska, M. Nowacka, I. Wilińska, W. Kubissa, V. Antonovich, J. Therm. Anal. Calorim. 105 (2011) 129–140.
F.A. Cardoso, M.D.M. Innocentini, M.M. Akiyoshi, V.C. Pandolfelli, J. Eur. Ceram. Soc. 24 (2004) 2073–2078.
P. Garcés, E.G. Alcocel, S. Chinchón, C.G. Andreu, J. Alcaide, Cem. Concr. Res. 27 (1997) 1343–1355.
Y. Li, L. Zhu, K. Liu, D. Ding, J. Zhang, G. Ye, Ceram. Int. 45 (2019) 12066–12071.
F. Hueller, J. Neubauer, S. Kaessner, F. Goetz-Neunhoeffer, J. Am. Ceram. Soc. 102 (2019) 4376–4387.
Y. Zhang, G. Ye, W. Gu, D. Ding, L. Chen, L. Zhu, J. Am. Ceram. Soc. 101 (2018) 2712–2717.
C. Gosselin, K.L. Scrivener, in: C.H. Fentiman, R.J. Mangabhai, K.L. Scrivener (Eds.), Calcium Aluminate Cement: Proceedings of the Centenary Conference, HIS BRE Press, Avignon, France, 2008, pp. 109–122.
M. Collepardi, S. Monosi, P. Piccioli, Cem. Concr. Res. 25 (1995) 961–968.
B. Touzo, F. Simonin, C. Wöhrmeyer, C. Parr, in: Proceedings of the Unified International Technical Conference on Refractories, Orlando, Florida, USA, 2005, pp. 35–39.
N. Li, X. Wang, Y. Mu, R. Zhang, L. Zhu, G. Ye, Constr. Build. Mater. 266 (2021) 120962.
N. Ding, L. Jin, J. Zhang, Concrete (2013) No. 10, 128–132
N. Ukrainczyk, T. Matusinovic, S. Kurajica, B. Zimmermann, J. Sipusic, Thermochim. Acta 464 (2007) 7–15.
Acknowledgements
The authors thank the National Natural Science Foundation of China (52172030) for the financial support.
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Zhang, Zz., Wang, Xy., Chu, Sz. et al. Effect of water loss during curing on hydration reaction and hydrates conversion in calcium aluminate cement-bonded castables. J. Iron Steel Res. Int. (2024). https://doi.org/10.1007/s42243-023-01161-7
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s42243-023-01161-7