Abstract
Superhydrophobic materials are severely limited in their applications due to their weak mechanical properties and complex preparation process. In this paper, polystyrene/fluorinated silica (PS/SiO2) superhydrophobic composite coatings were prepared on the surface of 304 stainless steel using a simple one-step spraying method. The effects of different PS contents on the wettability as well as the wear properties of the samples were investigated. SiO2 was encapsulated in polystyrene to form a structure similar to cement encapsulated stones. With the addition of PS, a mound-like structure was formed on the sample surface, and a more optimized micro–nano structure was obtained when the content of PS was 0.6 g. At this time, the sample exhibited excellent wettability with a contact angle of 157.86° and a sliding angle of 0.84°. In addition, the contact angle of 151.09° was achieved after 180 cm of friction under a 100 g load and the composite coating prepared by this method also has excellent chemical stability, water impact resistance, corrosion resistance, and self-cleaning properties. This opens up new possibilities for the development of simple and robust superhydrophobic materials.
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References
Zhao, J., Sun, R. Y., Liu, C., & Mo, J. L. (2022). Application of ZnO/epoxy resin superhydrophobic coating for buoyancy enhancement and drag reduction. Colloids and Surfaces a-Physicochemical and Engineering Aspects, 651, 129714.
Yin, H. W., Liu, H., Guo, X. H., Cui, Z., Tang, J. T., Lin, X. Z., & Hu, C. B. (2022). A facile approach to fabricate robust superhydrophobic Cu/TiO2 composite coating on stainless steel. Vacuum, 195, 110699.
Su, H., Luan, B. R., Dong, Y. Y., Zhang, X. M., Liu, Z. G., & Wang, C. (2022). Lotus leaf-like Ni-decorated SiC with combined superhydrophobicity and enhanced microwave absorption performance. Colloids and Surfaces a-Physicochemical and Engineering Aspects, 650, 129602.
Jing, X. B., Xia, Y. N., Chen, F. Z., Yang, C. J., Yang, Z., & Jaffery, S. H. I. (2022). Preparation of superhydrophobic glass surface with high adhesion. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 633, 127861.
Wang, X. D., Dai, L. G., Jiao, N. D., Tung, S., & Liu, L. Q. (2021). Superhydrophobic photothermal graphene composites and their functional applications in microrobots swimming at the air/water interface. Chemical Engineering Journal, 422, 129394.
Han, Z., Fu, J., Wang, Z., Wang, Y. G., Li, B., Mu, Z. Z., & Niu, S. C. (2017). Long-term durability of superhydrophobic properties of butterfly wing scales after continuous contact with water. Colloids and Surfaces a-Physicochemical and Engineering Aspects., 518, 139–144.
Krishnan, A., Krishnan, A. V., Ajith, A., & Shibli, S. M. A. (2021). Influence of materials and fabrication strategies in tailoring the anticorrosive property of superhydrophobic coatings. Surfaces and Interfaces, 25, 101238.
Gong, B. C., Ma, L. J., Guan, Q., Tan, R., Wang, C., Wang, Z. B., & Zeng, G. S. (2022). Preparation and particle size effects study of sustainable self-cleaning and durable silicon materials with superhydrophobic surface performance. Journal of Environmental Chemical Engineering., 10(3), 107884.
Peethan, A., Pais, M., Rao, P. D. L. T., Singh, K., & George, S. D. (2022). Wettability tailored superhydrophobic and oil-infused slippery aluminium surface for improved anti-corrosion performance. Materials Chemistry and Physics, 290, 126517.
Liu, X., Zhang, D. K., & Guo, Z. G. (2020). A facile modifier-free approach to fabricate antistatic superhydrophobic composite coatings with remarkable thermal stability and corrosion resistance. Journal of Bionic Engineering, 17(3), 421–435.
Deshmukh, S., Banerjee, D., Quintero, J. S. M., Fishlock, S. J., McLaughlin, J., Waghmare, P. R., & Roy, S. S. (2021). Polarity dependent electrowetting for directional transport of water through patterned superhydrophobic laser induced graphene fibers. Carbon, 182, 605–614.
Zhang, R. L., Zhou, Z. P., Wang, Y., Dai, X. H., Chen, L., & Dai, J. D. (2021). One-step condensation/copolymerization of VTES and DVB for self-assembly bionic superhydrophobic surface coating and study on oil-water separation. Journal of Bionic Engineering, 18(3), 559–573.
Wang, P., Li, Z. Q., Xie, Q., Duan, W., Zhang, X. C., & Han, H. L. (2021). A passive anti-icing strategy based on a superhydrophobic mesh with extremely low ice adhesion strength. Journal of Bionic Engineering, 18(1), 55–64.
Jin, K. L., Zhang, M., Wang, J., Jin, Z. H., Sun, J. F., Zhao, Y. P., & Cai, Z. S. (2022). Robust highly conductive fabric with fluorine-free healable superhydrophobicity for the efficient deicing of outdoor’s equipment. Colloids and Surfaces a-Physicochemical and Engineering Aspects., 651, 129639.
Xiao, Z., Xu, D., Zhang, W. W., Yu, X. Q., & Zhang, Y. F. (2021). Dip-coating of superhydrophobic surface on irregular substrates for dropwise condensation. Journal of Bionic Engineering, 18(2), 387–397.
Chen, Z., Wu, C., Zhou, H. B., Zhang, G. J., & Yan, H. Z. (2022). A high-efficiency preparation method of super wear-resistant superhydrophobic surface with hierarchical structure using wire electrical discharge machining. Surface & Coatings Technology, 444, 128673.
Wu, Z. W., Shen, Y. Z., Tao, J., Jia, Z. F., Chen, H. F., Jiang, J. W., & Wang, Z. (2021). Green synthesis of mechanical robust superhydrophobic CNT@PU coatings with high flexibility for extensive applications. Journal of Bionic Engineering, 18(1), 40–54.
Shen, Y. Z., Li, K. L., Chen, H. F., Wu, Z. W., & Wang, Z. (2021). Superhydrophobic F-SiO2@PDMS composite coatings prepared by a two-step spraying method for the interface erosion mechanism and anti-corrosive applications. Chemical Engineering Journal, 413, 127455.
Chen, Z., Yan, Z. J., Zhou, H. B., Han, F. L., Zhao, L. H., & Yan, H. Z. (2021). One-step fabrication of the wear-resistant superhydrophobic structure on SiCp/Al composite surface by WEDM. Surface & Coatings Technology, 409, 126876.
Huang, J. Y., & Yang, S. (2022). Investigation on anisotropic tribological properties of superhydrophobic/superlipophilic lead bronze surface textured by femtosecond laser. Applied Surface Science, 579, 152223.
Ma, Y. W., & He, Q. (2022). Preparation of superhydrophobic conductive CNT/PDMS film on paper by foam spraying method. Colloids and Surfaces a-Physicochemical and Engineering Aspects, 648, 129327.
Xue, F. X., Shi, X. T., Bai, W. X., Li, J. E., Li, Y. W., Zhu, S. Y., & Feng, L. B. (2022). Enhanced durability and versatile superhydrophobic coatings via facile one-step spraying technique. Colloids and Surfaces a-Physicochemical and Engineering Aspects., 640, 128411.
Zhu, P., Zhu, L. J., Ge, F. F., Wang, G., & Zeng, Z. X. (2022). Sprayable superhydrophobic coating with high mechanical/chemical robustness and anti-corrosion. Surface & Coatings Technology, 443, 128609.
Li, H., Xin, L., Zhang, K., Yin, X. L., & Yu, S. R. (2022). Fluorine-free fabrication of robust self-cleaning and anti-corrosion superhydrophobic coating with photocatalytic function for enhanced anti-biofouling property. Surface & Coatings Technology, 438, 128406.
Yu, X. F., Shi, X. T., Xue, F. X., Bai, W. X., Li, Y. W., Liu, Y. H., & Feng, L. B. (2021). SiO2 nanoparticle-containing superhydrophobic materials with enhanced durability via facile and scalable spray method. Colloids and Surfaces a-Physicochemical and Engineering Aspects, 626, 127014.
Han, B., Wang, H. Y., Yuan, S. C., Li, Y., Zhang, X. G., Lin, D., & Zhu, Y. J. (2020). Durable and anti-corrosion superhydrophobic coating with bistratal structure prepared by ambient curing. Progress in Organic Coatings., 149, 105922.
Zhang, X. H., Wei, C. J., Ma, S. Y., Zhang, C. X., Li, Y., Chen, D. J., & Huang, X. J. (2021). Janus poly(vinylidene fluoride)-graft-(TiO2 nanoparticles and PFDS) membranes with loose architecture and asymmetric wettability for efficient switchable separation of surfactant-stabilized oil/water emulsions. Journal of Membrane Science., 640, 119837.
Chen, P., Wu, L., Gao, J., Feng, C. Q., Yu, B. J., & Qian, L. M. (2021). An improved scanning probe-based lithography: Site-controlled formation of self-assembled film as an etch mask. Microelectronic Engineering, 244, 111560.
Li, G. J., Jiang, B., Liu, H. Q., Ning, L., Yi, D. Q., Wang, X. M., & Liu, Z. Y. (2019). Superhydrophobic surface with lotus/petal effect and its improvement on fatigue resistance of heat-resistant steel. Progress in Organic Coatings, 137, 105315.
Xia, M. C., Yang, T., Chen, S. Y., & Yuan, G. M. (2020). Fabrication of superhydrophobic Eucalyptus wood surface with self-cleaning performance in air and oil environment and high durability. Colloid and Interface Science Communications, 36, 100264.
Du, J. J., Yuan, H. X., Xia, H., Kou, H. J., Zhang, Y. Z., Xing, W. L., & Zhang, C. (2022). Improvement of superhydrophobicity and durability of EP+PDMS/SiO2 composite coatings by adjusting laser curing powers. Materials Chemistry and Physics, 289, 126428.
Wang, L. L., Liu, C. C., Bai, Z. X., Huang, Y. M., & Liu, X. B. (2022). Superhydrophobic ZIF-8/PEN films with ultralow dielectric constant and outstanding mechanical properties. Composites Science and Technology, 225, 109498.
Wang, N., Wang, Q., Xu, S. S., & Lei, L. L. (2021). Green fabrication of mechanically stable superhydrophobic concrete with anti-corrosion property. Journal of Cleaner Production, 312, 127836.
Myint, M. T., Hornyak, G. L., & Dutta, J. (2014). One pot synthesis of opposing “rose petal” and “lotus leaf” superhydrophobic materials with zinc oxide nanorods. Journal of Colloid and Interface Science, 415, 32–38.
Shao, Y. L., Zhao, J., Fan, Y., Wan, Z. P., Lu, L. S., Zhang, Z. H., & Ren, L. Q. (2020). Shape memory superhydrophobic surface with switchable transition between “Lotus Effect” to “Rose Petal Effect.” Chemical Engineering Journal., 382, 122989.
Liu, Y. B., Cao, X. F., Shi, J. K., Shen, B. B., Huang, J. Y., Hu, J., & Lai, Y. K. (2022). A superhydrophobic TPU/CNTs@SiO2 coating with excellent mechanical durability and chemical stability for sustainable anti-fouling and anti-corrosion. Chemical Engineering Journal., 434, 134605.
Tang, Y. P., Cai, Y. K., Wang, L., Luo, X. C., Wang, B., Song, Q. H., & Liu, Z. Q. (2022). Formation mechanism of superhydrophobicity of stainless steel by laser-assisted decomposition of stearic acid and its corrosion resistance. Optics and Laser Technology, 153, 108190.
An, K., Sui, Y., Wang, Y. Q., Qing, Y. Q., Long, C., Liu, X. Y., & Liu, C. S. (2022). Synergistic control of wetting resistance and corrosion inhibition by cerium to enhance corrosion resistance of superhydrophobic coating. Colloids and Surfaces a-Physicochemical and Engineering Aspects., 653, 129874.
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This study was supported by the National Natural Science Foundation of China (Grant Number 52172090 and 52071159).
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Wang, Y., Yu, L., Xu, J. et al. Robust Polystyrene/Fluorinated Silica Superhydrophobic Composite Coatings with Rapid Curing at Room Temperature Prepared by One-Step Spraying. J Bionic Eng 20, 2742–2754 (2023). https://doi.org/10.1007/s42235-023-00396-0
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DOI: https://doi.org/10.1007/s42235-023-00396-0