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Multifunctional flexible, crosslinked composites composed of trashed MXene sediment with high electromagnetic interference shielding performance

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Abstract

Developing novel nanomaterials for constructing multifunctional macrostructures in a facile, energy-efficient, sustainable, and scalable approach is urgently demanded yet remains highly challenging. Here, a type of freestanding, robust, highly flexible composite films composed of “trashed” MXene sediment (MS) are prepared in an ambient pressure casting approach. The typical green polymer of polyvinyl alcohol is employed to demonstrate the high potential of MS for constructing films with multifunctionalities, including electrically conductive, hydrophobic, photothermal, and electromagnetic interference (EMI) shielding performance. Upon the synergy of surface terminal functional groups, local defects, and numerous heterogeneous interfaces, the MS-based composites can have EMI shielding effectiveness (SE) of 76.2 dB in the X-band at the thickness of merely 590 µm and efficient SE value in the ultrabroadband frequency range of 8.2 to 40 GHz. Moreover, the EMI SE of the MS-based composites is widely controlled by adjusting the MS contents and film thickness. Combined with the sensitive and reliable photothermal performance, this work thus demonstrates a cost-effective, sustainable, and scalable strategy to prepare a type of multifunctional MS-based films with application potentials in thermal therapy, wearable electronics, electromagnetic compatible, and aerospace.

Graphical Abstract

The freestanding, yet robust and highly flexible composite films for EMI shields, which exhibits excellent mechanical strength and flexibility, good hydrophobicity, and water resistance.

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Acknowledgements

The authors acknowledge the assistance of Shandong University Testing and Manufacturing Center for Advanced Materials.

Funding

This work was financially supported by the National Key R&D Program of China (No. 2021YFB3502500), National Natural Science Foundation of China (No. 22205131), Natural Science Foundation of Shandong Province (No. 2022HYYQ-014), Provincial Key Research and Development Program of Shandong (No. 2019JZZY010312, 2021ZLGX01), New 20 Funded Programs for Universities of Jinan (No. 2021GXRC036), and the Qilu Young Scholar Program of Shandong University (No. 31370082163127).

Author information

Authors and Affiliations

  1. Key Laboratory for Liquid–Solid Structural Evolution and Processing of Materials, Ministry of Education and School of Materials Science and Engineering, Shandong University, Jinan, People’s Republic of China

    Sinan Zheng, Yue Liu, Yunfei Yang, Bin Li, Jiurong Liu & Zhihui Zeng

  2. Department of Chemistry and Applied Biosciences, ETH Zurich, CH-8093, Zurich, Switzerland

    Na Wu

  3. Science and Technology on Electromagnetic Compatibility Laboratory, China Ship Development and Design Centre, Wuhan, People’s Republic of China

    Qilei Wu

  4. College of Science, Civil Aviation University of China, Tianjin, People’s Republic of China

    Chenxi Hu

Authors
  1. Sinan Zheng
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  2. Na Wu
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  3. Yue Liu
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  4. Qilei Wu
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  5. Yunfei Yang
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  6. Bin Li
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  7. Chenxi Hu
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  8. Jiurong Liu
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  9. Zhihui Zeng
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Contributions

Sinan Zheng: conceptualization, formal analysis, writing—original draft. Na Wu: investigation. Yue Liu: methodology. Qilei Wu: resources. Yunfei Yang: software. Bin Li: validation. Chenxi Hu: supervision. Jiurong Liu: project administration. Zhihui Zeng: writing—review and editing.

Corresponding authors

Correspondence to Na Wu, Jiurong Liu or Zhihui Zeng.

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Zheng, S., Wu, N., Liu, Y. et al. Multifunctional flexible, crosslinked composites composed of trashed MXene sediment with high electromagnetic interference shielding performance. Adv Compos Hybrid Mater 6, 161 (2023). https://doi.org/10.1007/s42114-023-00741-1

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  • DOI: https://doi.org/10.1007/s42114-023-00741-1

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