Abstract
The first time machine learning-based refractive index model proposed based on the density parameter using a glass dataset of 2000 oxide glass samples to predict refractive index of the xZnF2-(20-x)ZnO-40As2O340TeO2. The study uses various machine learning techniques such as gradient decent, artificial neural network, and random forest regression to predict the refractive index and density of glasses. The random forest regression (RFR) model is found to be the most effective with a maximum R2 value of 0.950 in the case of refractive index prediction and 0.926 for density prediction. The study also investigates the effects of nitrogen ion implantation on the glasses, finding that increased nitrogen dose causes a reduction in density and an increase in refractive index. The glass transition temperature decreases with increased nitrogen dose, possibly due to implantation defects. However, the glass stability increases with increasing implantation dose for low and high fluorine content glasses, likely due to the development of band gap defect levels and an increase in carrier concentration.
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Data availability on request and preview of dataset is available on website https://www.nridg.com/.
References
Borsa, F., Torgeson, D.R., Martin, S., Patel, H.: Phys. Rev. B 46, 795 (1992). https://doi.org/10.1103/PhysRevB.46.795
Dimitriev, Y., Wright, A.C., Mihailova, V., Gattef, E., Guy, C.A.: An X-ray diffraction study of bismuthate glasses. J Mater Sci Lett 14, 347–350 (1995). https://doi.org/10.1007/BF00592146
Cheng, Y., Xiao, H.: Wenming Guo, Weiming Guo, Structure and crystallization kinetics of Bi2O3–B2O3 glasses. Thermochim. Acta 444, 173 (2006)
Zheng, H., Mackenzie, J.D.: Phys. Rev. B 38, 7166 (1988). https://doi.org/10.1103/PhysRevB.38.7166
Koubisy, M.S.I., Zatsepin, A.F., Yu Biryukov, D., Zatsepin, D.A., Shtang, T.V.: J. Non-Cryst. Solids 563, 120818 (2021). https://doi.org/10.1016/j.jnoncrysol.2021.120818
Svecova, B., Nekvindova, P., Mackova, A., Malinsky, P., Kolitsch, A., Machovic, V., Stara, S., Mika, M., Spirkova, J.: J. Non-Cryst. Solids 356, 2468 (2010). https://doi.org/10.1016/j.jnoncrysol.2010.03.031
Bogomolova, L.D., Yu Tepliakov, G., Caccavale, F.: J. Non-Cryst. Solids 194, 291 (1996). https://doi.org/10.1016/0022-3093(95)00496-3
Li, H., Tomozawa, M., Lou, V.K.: J. Non-Cryst. Solids 168, 56 (1994). https://doi.org/10.1016/0022-3093(94)90120
Jia, H., Muntele, C.I., Huang, L., Li, X., Li, G., Zhang, T., He, W., Liaw, P.K.: A study on the surface structures and properties of Ni-free Zr-based bulk glasses after Ar and Ca ion implantation. Intermetallics 41, 35 (2013). https://doi.org/10.1016/j.intermet.2013.04.010
Trieloff, M., Falter, M., Jessberger, E.K.: The distribution of mantle and atmospheric argon in oceanic basalt glasses. Geochimica et Cosmochimica Acta 67, 1237–1253 (2003). https://doi.org/10.1016/S0016-7037(02)01286-3
Husinsky, W., Ajami, A., Nekvindova, P., Svecova, B., Pesicka, J., Janecek, M.: Z-scan study of nonlinear absorption of gold nano-particles prepared by ion implantation in various types of silicate glasses. Opt. Commun. 285, 2729–2733 (2012). https://doi.org/10.1016/j.optcom.2012.01.044
Tóth, Z.-R., Feraru, A., Debreczeni, D., Todea, M., Popescu, R.A., Gyulavári, T., Sesarman, A., Negrea, G., Vodnar, D.C., Hernadi, K., Pap, Z., Baia, L., Magyari, K.: Influence of different silver species on the structure of bioactive silicate glasses. J. Non-Cryst. Solids 583, 121498 (2022). https://doi.org/10.1016/j.jnoncrysol.2022.121498
Liu, C.-X., Zhang, J., Lin, S.-B., Yue, Q.-Y., Zheng, R.-L., Guo, J.-H.: Two-dimensional waveguides in magneto-optical glasses fabricated by carbon ion implantation and femtosecond laser ablation. Opt. Commun. 495, 127109 (2021). https://doi.org/10.1016/j.optcom.2021.127109
Ahmmad, S.K., Magudapathy, P., Edukondalu, A., et al.: Nitrogen implantation of zinc arsenic tellurite glasses. J. Aust. Ceram. Soc. 57, 185–194 (2021). https://doi.org/10.1007/s41779-020-00515-8
Hosono, H.: Structural defects and the state of implanted ions in silica glasses implanted with silicon and/or nitrogen ions. Nucl. Instrum. Methods Phys. Res., Sect. B 65, 375–379 (1992). https://doi.org/10.1016/0168-583X(92)95069-4
Chengyu, W.: TaoYing, WangShuchu, Effect of nitrogen ion-implantation on silicate glasses. J. Non-Cryst. Solids 52, 589–603 (1982). https://doi.org/10.1016/0022-3093(82)90336-2
Pei-HungKuo, S.-Y., Duh, J.-G.: Bio-compatible zirconium-based thin film metallic glasses with nitrogen reinforced by micro-alloying technique. Materials 272, 124965 (2021)
Bogomolova, L.D., Jachkin, V.A., Prushinsky, S.A., Stefanovsky, S.V., Yu Teplyakov, G., Caccavale, F.: EPR study of paramagnetic species in oxide glasses implanted with nitrogen. J. Non-Cryst. Solids 220, 109–126 (1997). https://doi.org/10.1016/S0022-3093(97)00259-7
Alzahrani, J.S., Eke, C., Alrowaili, Z.A., Boukhris, I., Mutuwong, C., Bourham, M.A., Al-Buriahi, M.S.: A theoretical study on the radiation shielding performance of borate and tellurite glasses. Solid State Sci. 129, 106902 (2022). https://doi.org/10.1016/j.solidstatesciences.2022.106902
Çağlar, İ, Cengiz, G.B., Bilir, G.: Gamma radiation shielding properties of some binary tellurite glasses. J. Non-Cryst. Solids 574, 121139 (2021). https://doi.org/10.1016/j.jnoncrysol.2021.121139
Tagiara, N.S., Palles, D., Simandiras, E.D., Psycharis, V., Kyritsis, A., Kamitsos, E.I.: J. Non. Solids 457, 116–125 (2017). https://doi.org/10.1016/j.jnoncrysol.2016.11.033
Gaikwad, D.K., Sayyed, M.I., Obaid, S.S., Issa, S.A.M., Pawar, P.P.: J. Alloys Compd. 765, 451–458 (2018). https://doi.org/10.1016/j.jallcom.2018.06.240
Desirena, H., Schulzgen, A., Sabet, S., Ramos-Ortiz, G., de la Rosa, E., Peyghambarian, N.: Opt. Mater. (2008). https://doi.org/10.1016/j.optmat.2008.08.005
Sharaf El-Deen, L.M., Al Salhi, M.S., Elkholy, M.M.: J. Alloy. Comp. 465, 333–339 (2008). https://doi.org/10.1016/j.jallcom.2007.10.104
Lakshminarayana, G., Yang, H., Qiu, J.: J. Alloy. Comp. 475, 569–576 (2009). https://doi.org/10.1016/j.jssc.2008.11.020
Yousef, E., Hotzel, M., Russel, C., Non-Cryst, J.: Solids 353, 333–338 (2007). https://doi.org/10.1016/j.jnoncrysol.2006.12.009
Edukondalu, A., Rahman, S., Ahmmad, S.K., Gupta, A., Siva-Kumar, K.: J. Taibah Univ. Sci. 10, 363–368 (2016). https://doi.org/10.1016/j.jtusci.2015.03.012
Berneschi, S., Brenci, M., Nunzi Conti, G., Pelli, S., Righini, G.C., Bettinelli, M., Speghini, A., Bányász, I., Fried, M., Khanh, N.Q., Pászti, F., Watterich, A., Leto, A., Pezzotti, G., Porporati, A.A.: Adv. SciTechnol. V55, 68–73 (2008). https://doi.org/10.4028/www.scientific.net/AST.55.68
Sun, K.-H.: calculation of refractive index of a glass as a direct function of its composition. J. Am. Ceram. Soc. 30, 282–287 (1974). https://doi.org/10.1111/j.1151-2916.1947.tb19655.x
Huang, Y.Y., Sarkar, A.: J. Non-Cryst. Solids 27, 29–37 (1978). https://doi.org/10.1016/0022-3093(78)90033-9
Ritland, H.N.: Relation between refractive index and density of a glass at constant temperature. J. Am. Ceram. Soc. 38, 86–88 (1955). https://doi.org/10.1111/j.1151-2916.1955.tb14581.x
Wen, Z., Curran, J.M., Harbison, S.-A., Wevers, G.: Bayesian mixture modelling for glass refractive index measurement. Sci. Justice 61, 345–355 (2021). https://doi.org/10.1016/j.scijus.2021.05.002
Deng, B.: J. Non-Cryst. Solids 529, 119768 (2020). https://doi.org/10.1016/j.jnoncrysol.2019.119768
Zhang, Y., Li, A., Deng, B., Hughes, K.K.: Npj Mater. Degrad. 4, 1–11 (2020). https://doi.org/10.1038/s41529-020-0118-x
Ahmmad, S.K., Jabeen, N., Uddin Ahmed, S.T., Ahmed, S.A., Rahman, S.: Ceram. Int. 47, 7946–7956 (2021). https://doi.org/10.1016/j.ceramint.2020.11.144
Shi, Y., Tandia, A., Deng, B., Elliott, S.R., Bauchy, M.: Acta Mater. 195, 252–262 (2020). https://doi.org/10.1016/j.actamat.2020.05.047
Cassar, D.R., Santos, G.G., Zanotto, E.D.: Designing optical glasses by machine learning coupled with a genetic algorithm. Ceram. Int. 47, 10555–10564 (2021). https://doi.org/10.1016/j.ceramint.2020.12.167
Ahmmad, S.K., Jabeen, N., Ahmed, S.T.U., Hussainy, S.F., Ahmed, B.: Ceram. Int. 47, 30172–30177 (2021). https://doi.org/10.1016/j.ceramint.2021.07.196
Ahmed, S.A., Rajiya, S., Samee, M.A., et al.: Density of bismuth boro zinc glasses using machine learning techniques. J Inorg Organomet Polym 32, 941–953 (2022). https://doi.org/10.1007/s10904-021-02183-y
Ahmmad, S.K., Alsaif, N.A.M., Shams, M.S., El Refaey, A.M., Elsad, R.A., Rammah, Y.S., Sadeq, M.S.: Opt. Mater. 134, 113145 (2022). https://doi.org/10.1016/j.optmat.2022.113145
Alsaif, N., Ahmmad, S.K., Khattari, Z.Y., Abdelghany, A.M., El-Refaey, A.M., Rammah, Y.S., Shams, M.S., Elsad, R.A.: Opt. Mater. 137, 113599 (2023). https://doi.org/10.1016/j.optmat.2023.113599
McCloy, J.S.: Methods for prediction of refractive index in glasses for the infrared, Proc. SPIE 8016, Window and Dome Technologies and Materials XII, 80160G (2011). https://doi.org/10.1117/12.882536
Bhattacharya, P.K., Sarma, N., Wagh, A.G.: Effect of ion implantation on the refractive index of glass. Pramana – J. Phys. 6, 102–108 (1976). https://doi.org/10.1007/BF02848640
Weeks, R.A., Hosono, H., Zuhr, R., et al.: Correlation between optical absorption and refractive index of silica and silicate glasses implanted with copper. MRS Online Proc. Libr. 152, 115–120 (1989). https://doi.org/10.1557/PROC-152-115
Shen, X.-l, Wang, Y., Zhu, Q.-f, et al.: Optical waveguides in fluoride lead silicate glasses fabricated by carbon ion implantation. Optoelectron. Lett. 14, 104–108 (2018). https://doi.org/10.1007/s11801-018-7215-x
Ahmmad, S.K., Taqiullah, S.M., Same, M.A., Balakrishnan, S., Rahman, S.: Phys. Chem. Glasses Eur. J. Glass Sci. Technol. B 56(6), 267–270 (2015). https://doi.org/10.13036/17533562.56.5.267
Effendy, N., Aziz, S.H.A., Kamari, H.M., Zaid, M.H.M., Budak, C.E.A., Shabdin, M.K., Khiri, M.Z.A., Wahab, S.A.A.: J. Market. Res. 9, 14082–14092 (2020). https://doi.org/10.1016/j.jmrt.2020.09.107
Acknowledgements
One of the author (Shaik Kareem Ahmmad) wishes to thank Prof. M.G. Krishna, University of Hyderabad for providing DSC facility and IGCAR Kalpakkam for providing implantation facility.
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Ahmmad, S.K., Nataraju, G., Siddiqui, N. et al. Machine learning refractive index model and nitrogen implantation studies of zinc arsenic tellurite glasses. J Aust Ceram Soc 59, 1443–1452 (2023). https://doi.org/10.1007/s41779-023-00928-1
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DOI: https://doi.org/10.1007/s41779-023-00928-1