Abstract
Sustainability in construction materials is a hot topic of research, and alkali-activated materials are believed to be a real alternative to OPC concrete. The manufacturing process of cement emits nearly 8% of CO2 into the atmosphere. This study utilised slag as a base binder in the alkali-activated mortar (AAM). The pumice powder was used as a replacement ratio of (0, 10, and 20) % by the mass of the slag. Three various ratios of alkali solution-to-binder ratio (s/b) were utilised (0.4, 0.5, and 0.6) for a detailed evaluation of the fresh and hardened properties of alkali-activated mortar. The setting time and flow test were conducted, and the mechanical characteristics were investigated through compressive strength, flexural strength, and direct tensile strength. Furthermore, fire resistance, water absorption, water sorptivity, porosity, density, efflorescence, and sulphate resistance were all examined to evaluate the durability characteristics of AAM. Results showed that increasing the amount of pumice powder in the mixture reduced its flowability for all s/b ratios. At a s/b of 0.4, increasing the pumice powder concentration degraded the mechanical and durability qualities. Simultaneously, increasing the amount of pumice powder at both s/b of 0.5 and 0.6 increased the mechanical and durability properties.
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Abbreviations
- AAM:
-
Alkali-activated mortar
- s/b:
-
Solution-to-binder ratio
- AAC:
-
Alkali-activated concrete
- OPC:
-
Ordinary Portland cement
- g:
-
Gram
- °C:
-
Degree Celsius
- hr:
-
Hour
- MPa:
-
Mega pascal
- SEM:
-
Scanning electronic microscopy
- GGBFS:
-
Ground-granulated blast furnace slag
References
Abdollahnejad Z, Luukkonen T, Mastali M, Kinnunen P, Illikainen M (2018) Development of one-part alkali-activated ceramic/slag binders containing recycled ceramic aggregates. J Mat Civ Eng 31(2):4018386
Aljanabi M, Çevik A, Nicş A, Bakbak D, Kadhim S (2022) Residual mechanical performance of lightweight fiber-reinforced geopolymer mortar composites incorporating expanded clay after elevated temperatures. J Com Mat 56(11):1737–1752
Allen G (2015) Hydraulic lime mortar for stone, brick and block Masonry: a best practice guide. Routledge, Oxfordshine
Al-Zboon KK, Al-smadi BM, Al-Khawaldh S (2016) Natural volcanic tuff-based geopolymer for Zn removal: adsorption isotherm, kinetic, and thermodynamic study. Water, Air, & Soil Poll 227(7):1–22
Alzeebaree R et al (2021) Using of recycled clay brick/fine soil to produce sodium hydroxide alkali activated mortars. Adv Stru Eng 24(13):2996
Ameri F, Shoaei P, Zareei SA, Behforouz B (2019) Geopolymers vs. alkali-activated materials (AAMs): a comparative study on durability, microstructure, and resistance to elevated temperatures of lightweight mortars. Con Buil Mat 222:49–63
Antoni A, Purwantoro AAT, Suyanto WSPD, Hardjito D (2020) Fresh and hardened properties of high calcium fly ash-based geopolymer matrix with high dosage of borax. Ira J Sci Tech, Tra Civ Eng 44(1):535–543
ASTM C1585 - 04E (2004) Standard test method for Measurement of rate of absorption of water by hydraulic‐cement concretes. ASTM International, West Conshohocken, PA
ASTM C348 - 18 (2018) Standard test method for flexural strength of hydraulic-cement mortars standard test method for measurement the flaxural tensile strength of mortar
Bernal SA, Rodrguez ED, de Gutiérrez R, Provis JL (2012) Performance of alkali-activated slag mortars exposed to acids. J Sus Cem -Bas Mat 1(3):138–151
Bingöl SS, Bilim C, Atics CD, Durak U (2020) Durability properties of geopolymer mortars containing slag. Ira J Scie Tech, Tran Civ Eng 44(1):561–569
Chakkor O, Altan MF, Canpolat O (2022) Elevated temperature, freezing-thawing and mechanical properties of limestone, marble, and basalt powders reinforced metakaolin-red mud-based geopolymer mortars. Ira J Scie Tech Tran Civ Eng. https://doi.org/10.1007/s40996-021-00797-3
Chi M (2017) Effects of the alkaline solution/binder ratio and curing condition on the mechanical properties of alkali-activated fly ash mortars. Sci Eng Comp Mat 24(5):773–782
Clausi M, Fernández-Jiménez AM, Palomo A, Tarantino SC, Zema M (2018) Reuse of waste sandstone sludge via alkali activation in matrices of fly ash and metakaolin. Con Bui Mat 172:212–223
Davidovits J (1991) Geopolymers: inorganic polymeric new materials. J the Ana Calo 37(8):1633–1656
Davidovits J (2008) Geopolymer chemistry and applications (Geopolymer Institute, Saint-Quentin, France)
Degefu DM, Liao Z, Berardi U, Labbé G (2022) The effect of activator ratio on the thermal and hygric properties of aerated geopolymers. J Bu Eng 45:103414. https://doi.org/10.1016/J.JOBE.2021.103414
Djobo JNY, Elimbi A, Tchakouté HK, Kumar S (2016) Mechanical properties and durability of volcanic ash based geopolymer mortars. Con Buil Mat 124:606–614
Duxson P, Fernández-Jiménez A, Provis JL, Lukey GC, Palomo A, Van Deventer JSJ (2007) Geopolymer technology: the current state of the art. J Mat Sci 42(9):2917–2933. https://doi.org/10.1007/s10853-006-0637-z
El-Hassan H, Ismail N (2018) Effect of process parameters on the performance of fly ash/GGBS blended geopolymer composites. J Sust Cem -Bas Mat 7(2):122–140
Eren NA et al (2021) The effects of recycled tire rubbers and steel fibers on the performance of self-compacting alkali activated concrete. Per Poly Civ Eng. https://doi.org/10.3311/PPci.17601
Eren NA et al (2021) Fresh and hardened state performance of self-compacting slag based alkali activated concrete using nanosilica and steel fiber. J Com Mat. https://doi.org/10.1177/00219983211032390
Goldsworthy H, Zhu MIN (2009) Mortar studies towards the replication of Roman concrete. Arch 51(6):932–946
Guerrieri M, Sanjayan JG (2010) Behavior of combined fly ash/slag-based geopolymers when exposed to high temperatures. Fir Mat : an Inter Jo 34(4):163–175
Gülşan ME, Alzeebaree R, Rasheed AA, Niş A, Kurtoğlu AE (2019) Development of fly ash/slag based self-compacting geopolymer concrete using nano-silica and steel fiber. Con Bui Mat. https://doi.org/10.1016/j.conbuildmat.2019.03.228
Guo L, Wu Y, Xu F, Song X, Ye J, Duan P, Zhang Z (2020) Sulfate resistance of hybrid fiber reinforced metakaolin geopolymer composites. Com Part b: Eng 183:107689
Jha B, Singh DN (2011) A review on synthesis, characterization and industrial applications of flyash zeolites. J Ma Edu 33(1):65
Kabay N, Tufekci MM, Kizilkanat AB, Oktay D (2015) Properties of concrete with pumice powder and fly ash as cement replacement materials. Con Bui Mat 85:1–8
Kadhim S, Çevik A, Nicş A, Bakbak D, Aljanabi M (2022) Mechanical behavior of fiber reinforced slag-based geopolymer mortars incorporating artificial lightweight aggregate exposed to elevated temperatures. Con Bui Mat 315:125766
Kani EN, Allahverdi A, Provis JL (2012) Efflorescence control in geopolymer binders based on natural pozzolan. Cem Con Com 34(1):25–33
Kurtoğlu AE, Alzeebaree R, Aljumaili O, Niş A, Gülşan ME, Humur G, Çevik A (2018) Mechanical and durability properties of fly ash and slag based geopolymer concrete. Adv Con Con. https://doi.org/10.12989/acc.2018.6.4.345
Kurtoglu AE, Cevik A, Farhan OH, Alzeebaree R, Gülşan ME (2017) Sea water resistance of fly ash- and slag-based geopolymer concrete in Con: 2nd Inter Ene & Eng Con At: Gaziantep University, Gaziantep, Turkey, pp 273–279
Kwek SY, Awang H, Cheah CB (2021) Influence of liquid-to-solid and alkaline activator (sodium silicate to sodium hydroxide) ratios on fresh and hardened properties of alkali-activated palm oil fuel ash geopolymer. Mat 14(15):4253
Mahdi SN, Hossiney N, Abdullah MMAB (2022) Strength and durability properties of geopolymer paver blocks made with fly ash and brick kiln rice husk ash. Cas Stu Con Mat 16:e00800
Mason BJ (2012) The analysis of taupo pumice as an effective partial cement replacement in concrete
Mawlod AO (2020) Performance of one-part alkali activated recycled ceramic tile/fine soil binders. Adv Con Con 10(4):311–317
Mobasher N, Bernal SA, Provis JL (2016) Structural evolution of an alkali sulfate activated slag cement. J Nuc Mat 468:97–104
Mohamed R, Abd Razak R, Mustafa Al Bakri Abdullah M, Khimi Shuib R, Aida Mohd Mortar N, Wazien Ahmad Zailani W (2019) Investigation of heat released during geopolymerization with fly ash based geopolymer. IOP Conf Series: Mater Sci Eng 551:012093. https://doi.org/10.1088/1757-899X/551/1/012093
Nath P, Sarker PK (2015) Use of OPC to improve setting and early strength properties of low calcium fly ash geopolymer concrete cured at room temperature. Cem Con Com 55:205–214
Nesbitt HW, Young GM (1984) Prediction of some weathering trends of plutonic and volcanic rocks based on thermodynamic and kinetic considerations. Geo Cos Acta 48(7):1523–1534
Nis A, Eren NA, Çevik A (2021) Effects of nanosilica and steel fibers on the impact resistance of slag based self-compacting alkali-activated concrete. Cer Inter 47(17):23905–23918
Noushini A, Babaee M, Castel A (2016) Suitability of heat-cured low-calcium fly ash-based geopolymer concrete for precast applications. Mag Con Res 68(4):163–177
Pouhet R (2015) Formulation and durability of metakaolin-based geopolymers. Univ Toul III-Paul Sabatier, Uni Tou
Provis JL (2018) Alkali-activated binders. Cem Concr Res 114(40):48
Provis JL, Bernal SA (2014) Geopolymers and related alkali-activated materials. Ann l Rev Mat Res 44:299–327
Shi C, Day RL (1993) Chemical activation of blended cements made with lime and natural pozzolans. Cem Concr Rese 23(6):1389–1396
Sleiman H, Perrot A, Amziane S (2010) A new look at the measurement of cementitious paste setting by Vicat test. Cem Concr Res 40(5):681–686
Standard A (2008) ASTM C109-standard test method for compressive strength of hydraulic cement mortars ASTM Inte , West Conshohocken, PA
Tekin I (2016) Properties of NaOH activated geopolymer with marble, travertine and volcanic tuff wastes. Con Bui Mat 127:607–617
van Deventer JSJ (2015) Microstructure and durability of alkali-activated materials as key parameters for standardization. J Sus Cem-Bas Mat 4(2):116–128
Walkley B, San Nicolas R, Bernal S, Provis JL, van Deventer J (2015) Effect of MgO incorporation on the structure of synthetic alkali-activated calcium aluminosilicate binders in Conf. 27th Bienn. Natl. Conf. Concr. Inst. Aust
Winnefeld FB, Haha M, Le Saout G, Costoya M, Ko S-C, Lothenbach B (2015) Influence of slag composition on the hydration of alkali-activated slags. J Sus Cem-Bas Mat 4(2):85–100
Xinyan W, Yanghai S, Liang H (2022) Performance of geopolymer concrete activated by sodium silicate and silica fume activator. Cas Stu Con Mat 17:e01513
Yang T et al (2012) Mechanical property and structure of alkali-activated fly ash and slag blends. J Sus Cem-Bas Mat 1(4):167–178
Zamanabadi SN, Zareei SA, Shoaei P, Ameri F (2019) Ambient-cured alkali-activated slag paste incorporating micro-silica as repair material: effects of alkali activator solution on physical and mechanical properties. Con Buil Mat 229:116911
Zhao F-Q, Ni W, Wang H-J, Liu H-J (2007) Activated fly ash/slag blended cement. Reso, Conse Recy 52(2):303–313
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Mawlod, A.O., Bzeni, D.K.H.A. & Alzeebaree, R. Performance of Slag-Pumice-Based Alkali-Activated Mortar at Ambient Environment. Iran J Sci Technol Trans Civ Eng 47, 2131–2147 (2023). https://doi.org/10.1007/s40996-023-01061-6
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DOI: https://doi.org/10.1007/s40996-023-01061-6