Abstract
In this work, we compare nitrogen oxide (NO X ) emissions from vehicles equipped with 2013 and 2015 model year (MY) diesel engines and exhaust aftertreatment, both certified to the same emissions standards, over a variety of real-world drive cycles. Our study concludes that 2013MY and 2015MY buses achieved real-world NO X conversion efficiencies of 75 and 95%, respectively. Engine-out NO X levels remained unchanged between the two busses when driven over the same transit bus routes. Therefore, emissions reductions are attributed to greater NO X conversion efficiency by the exhaust aftertreatment system, especially in low catalyst temperature and transient response scenarios. Although it is likely that other transit buses and vocational vehicles will express different characteristics based on their specific operating conditions and powertrain setup; our results show that improvements to aftertreatment systems, in the areas of catalyst activity, aftertreatment controls, and urea dosing strategy can significantly reduce NO X emissions over the investigated real-world drive cycles.
Similar content being viewed by others
References
Grewe, V., Dahlmann, K., Matthes, S., Steinbrecht, W.: Attributing ozone to NOx emissions: implications for climate mitigation measures. Atmos. Environ. 59, 102–107 (2012). doi:10.1016/j.atmosenv.2012.05.002
US EPA, OAR, OAQPS (2014) Health | Nitrogen Dioxide | US EPA. In: Air Radiat. http://www.epa.gov/airquality/nitrogenoxides/health.html. Accessed 1 Dec 2014
Girard, J., Cavataio, G., Snow, R., Lambert, C.: Combined Fe-cu SCR systems with optimized ammonia to NOx ratio for diesel NOx control. SAE IntJFuels Lubr. 1, 603–610 (2008). doi:10.4271/2008-01-1185
Munnannur, A., Chiruta, M., Liu, Z.G.: Thermal and fluid dynamic considerations in aftertreatment system design for SCR solid deposit mitigation. SAE Tech Pap. (2012). doi:10.4271/2012-01-1287
Herman, A., Wu, M.-C., Cabush, D., Shost, M.: Model based control of SCR dosing and OBD strategies with feedback from NH 3 sensors. SAE Int J Fuels Lubr. 2, 375–385 (2009). doi:10.4271/2009-01-0911
Narayanaswamy K, He Y (2008) Modeling of Copper-Zeolite and Iron-Zeolite Selective Catalytic Reduction (SCR) Catalysts at Steady State and Transient Conditions. SAE Int. 2008-01-0615
Koebel, M., Elsener, M., Kleemann, M.: Urea-SCR: a promising technique to reduce NOx emissions from automotive diesel engines. Catal. Today. 59, 335–345 (2000). doi:10.1016/S0920-5861(00)00299-6
Girard, J., Snow, R., Cavataio, G., Lambert, C.: The influence of ammonia to NOX ratio on SCR performance. SAE Tech Pap. 2007-01-1581 (2007). doi:10.4271/2007-01-1581
Klingstedt, F., Arve, K., Murzin, D.Y.U.: Toward improved catalytic low-temperature NO x removal in diesel-powered vehicles. Acc. Chem. Res. 39, 273–282 (2006). doi:10.1021/ar050185k
Koebel, M., Elsener, M., Madia, G.: Reaction pathways in the selective catalytic reduction process with NO and NO2 at low temperatures. Ind. Eng. Chem. Res. 40, 52–59 (2001). doi:10.1021/ie000551y
Ettireddy, P.R., Kotrba, A., Spinks, T., et al.: Development of low temperature selective catalytic reduction (SCR) catalysts for future emissions regulations. SAE Tech Pap. 2014-01-1520 (2014). doi:10.4271/2014-01-1520
Kang, M., Park, E.D., Kim, J.M., Yie, J.E.: Cu-Mn mixed oxides for low temperature NO reduction with NH3. Catal. Today. 111, 236–241 (2006). doi:10.1016/j.cattod.2005.10.032
Kang, M., Park, E.D., Kim, J.M., Yie, J.E.: Manganese oxide catalysts for NOx reduction with NH3 at low temperatures. Appl. Catal. A Gen. 327, 261–269 (2007). doi:10.1016/j.apcata.2007.05.024
Peña, D.A., Uphade, B.S., Smirniotis, P.G.: TiO2-supported metal oxide catalysts for low-temperature selective catalytic reduction of NO with NH3: I. Evaluation and characterization of first row transition metals. J. Catal. 221, 421–431 (2004). doi:10.1016/j.jcat.2003.09.003
Yoshikawa, M., Yasutake, A., Mochida, I.: Low-temperature selective catalytic reduction of NO(x) by metal oxides supported on active carbon fibers. Appl Catal a-General. 173, 239–245 (1998)
Tang, X., Hao, J., Yi, H., Li, J.: Low-temperature SCR of NO with NH3 over AC/C supported manganese-based monolithic catalysts. Catal. Today. 126, 406–411 (2007). doi:10.1016/j.cattod.2007.06.013
Chi, J.N., Dacosta, H.F.M.: Modeling and control of a urea-SCR aftertreatment system reprinted from: diesel exhaust emission control modeling. SAE Tech Pap. 2005-01-0966 114, 449–464 (2005)
Chavannavar, P.: Development and implementation of a mapless, model based SCR control system. SAE Int. J. Engines. 7, 1113–1124 (2014). doi:10.4271/2014-01-9050
Muncrief, R.L., Rooks, C.W., Cruz, M., Harold, M.P.: Combining biodiesel and exhaust gas recirculation for reduction in NOx and particulate emissions. Energy and Fuels. 22, 1285–1296 (2008). doi:10.1021/ef700465p
Johnson, D.R., Bedick, C.R., Clark, N.N., Mckain, D.L.: Design and testing of an independently controlled urea SCR retrofit system for the reduction of NOx emissions from marine diesels. Environ Sci Technol. 43, 3959–3963 (2009). doi:10.1021/es900269p
Herner, J.D., Hu, S., Robertson, W.H., et al.: Effect of advanced aftertreatment for PM and NOx reduction on heavy-duty diesel engine ultrafine particle emissions. Environ Sci Technol. 45, 2413–2419 (2011). doi:10.1021/es102792y
Herner, J.D., Hu, S., Robertson, W.H., et al.: Effect of advanced aftertreatment for PM and NOx control on heavy-duty diesel truck emissions. Environ Sci Technol. 43, 5928–5933 (2009). doi:10.1021/es9008294
Yao, C., Cheung, C.S., Cheng, C., Wang, Y.: Reduction of smoke and NOx from diesel engines using a diesel/methanol compound combustion system. Energy and Fuels. 21, 686–691 (2007). doi:10.1021/ef0602731
Jeon, J., Lee, J.T., Park, S.: Nitrogen compounds (NO, NO2, N2O, and NH3 ) in NOx emissions from commercial EURO VI type heavy-duty diesel engines with a urea-selective catalytic reduction system. Energy Fuel. 30, 6828–6834 (2016). doi:10.1021/acs.energyfuels.6b01331
Kotz, A.J., Kittelson, D.B., Northrop, W.F.: Lagrangian hotspots of in-use NOx emissions from transit buses. Environ Sci Technol. 50, 5750–5756 (2016). doi:10.1021/acs.est.6b00550
Wu, Y., Zhang, S.J., Li, M.L., et al.: The challenge to NOx emission control for heavy-duty diesel vehicles in China. Atmos. Chem. Phys. 12, 9365–9379 (2012). doi:10.5194/acp-12-9365-2012
Misra, C., Collins, J.F., Herner, J.D., et al.: In-use NOx emissions from model year 2010 and 2011 heavy-duty diesel engines equipped with aftertreatment device. Environ Sci Technol. 47, 7892–7898 (2013) doi: 10.1021/es4006288
Posada F, Bandivadekar A (2015) Global overview of on-board diagnostic (OBD) systems for heavy-duty vehicles. In: Int. Counc. Clean Transp. http://www.theicct.org/sites/default/files/publications/ICCT_Overview_OBD-HDVs_20150209.pdf.
Stanton, D.W.: Systematic development of highly efficient and clean engines to meet future commercial vehicle greenhouse gas regulations. SAE Int. 2013-01-2421 (2013). doi:10.4271/2013-01-2421
U.S. Environmental Protection Agency (2008) Regulations Requiring Onboard Diagnostic Systems on 2010 and Later Heavy-Duty Engines Used in Highway Vehicles Over 14,000 Pounds; Revisions to Onboard Diagnostics Requirements for Diesel Highway Vehicles Under 14,000 Pounds.
Zhang, H., Wang, J., Wang, Y.-Y.: Removal of NOx sensor ammonia cross sensitivity from contaminated measurements in diesel-engine selective catalytic reduction systems. Fuel. 150, 448–456 (2015). doi:10.1016/j.fuel.2015.02.053
Zhang, H., Wang, J.: NOx sensor ammonia-cross-sensitivity factor estimation in diesel engine selective catalytic reduction systems. J. Dyn. Syst. Meas. Control. 137, 61015 (2015). doi:10.1115/1.4029347
Hsieh M-F (2010) Control of Diesel Engine Urea Selective Catalytic Reduction Systems.
Sensors Inc (2011) SEMTECH - DS. www.sensors-inc.com. Accessed 5 Mar 2017
O’Keefe, M.P., Simpson, A., Kelly, K.J., Pedersen, D.S.: Duty cycle characterization and evaluation towards heavy hybrid vehicle applications. SAE Tech Pap. 2007-01-0302 (2007). doi:10.4271/2007-01-0302
Society of Automotive Engineers (2012) J1939-71 Vehicle Application layer. SAE Int. J1939–71
Acknowledgments
The authors would like to acknowledge Twin Cities Metro Transit for allowing data collection from in-service transit buses, installing data logging equipment, and for providing access to bus route information. In particular, we would like to acknowledge David Haas at Metro Transit for his critical assistance in coordinating bus schedules and providing technical guidance on this project. We would also like to recognize Cummins Emission Solutions for funding this research and for providing insight and technical assistance throughout the project.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no competing interests.
Funding
This work was funded in part by Cummins Emission Solutions.
Rights and permissions
About this article
Cite this article
Kotz, A.J., Kittelson, D.B., Northrop, W.F. et al. Real-World NO X Emissions of Transit Buses Equipped with Diesel Exhaust Aftertreatment Systems. Emiss. Control Sci. Technol. 3, 153–160 (2017). https://doi.org/10.1007/s40825-017-0064-4
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40825-017-0064-4